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592684

双(二甲基膦)甲烷

Name: 双(二甲基膦)甲烷
Brand: ALDRICH

97%

别名:

DMPM

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关于此项目

线性分子式:

(CH₃)₂PCH₂P(CH₃)₂

化学文摘社编号:

64065-08-3

分子量:

136.11

NACRES:

NA.22

PubChem Substance ID:

24881405

UNSPSC Code:

12352001

MDL number:

MFCD00058731

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属性

Quality Level

100

assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.5060 (lit.)

bp

42 °C/12 mmHg (lit.)

density

0.86 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CP(C)CP(C)C

InChI

1S/C5H14P2/c1-6(2)5-7(3)4/h5H2,1-4H3

InChI key

MRNJHNUEBDGNEL-UHFFFAOYSA-N

说明

Application

Reactant for:

Preparation of ruthenium carbonyl hydrido phosphanido diphosphine dinuclear complexes
Luminescent face-to-face dinuclear platinum(II) alkynyl phosphine complexes
Phosphorus-phosphorus bond and nuclear spin-spin coupling
Formation of a catalytic ruthenium(II)-triphos complex

Catalyst for:

Asymmetric alkylation of racemic secondary phosphines
Palladium-diphosphine catalyzed carbonylation of ethene

pictograms

GHS02

signalword

Danger

hcodes

H250

pcodes

P222 - P231 - P422

Hazard Classifications

Pyr. Liq. 1

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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miR-380-5p-mediated repression of TEP1 and TSPYL5 interferes with telomerase activity and favours the emergence of an "ALT-like" phenotype in diffuse malignant peritoneal mesothelioma cells.

Graziella Cimino-Reale et al.

Journal of hematology & oncology, 10(1), 140-140 (2017-07-19)

Understanding the molecular/cellular underpinnings of diffuse malignant peritoneal mesothelioma (DMPM), a fatal malignancy with limited therapeutic options, is of utmost importance for the fruitful management of the disease. In this context, we previously found that telomerase activity (TA), which accounts

Impact of hypoxia on chemoresistance of mesothelioma mediated by the proton-coupled folate transporter, and preclinical activity of new anti-LDH-A compounds.

Giovanna Li Petri et al.

British journal of cancer, 123(4), 644-656 (2020-06-05)

Expression of proton-coupled folate transporter (PCFT) is associated with survival of mesothelioma patients treated with pemetrexed, and is reduced by hypoxia, prompting studies to elucidate their correlation. Modulation of glycolytic gene expression was evaluated by PCR arrays in tumour cells

Boron-Boron Dehydrocoupling of Boranes Initiated by Reaction with Iodine.

Jana Elias et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 25(26), 6553-6561 (2019-03-02)

A new boron-boron dehydrocoupling strategy was established, providing convenient access to some diborane(4) compounds starting from simple borane adducts under mild conditions. In contrast to the traditional pathway using a reducing reagent, the reduction from BIII to BII was paradoxically

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货号	GTIN
592684-1G	04061838128416