592684
双(二甲基膦)甲烷
97%
别名:
DMPM
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关于此项目
线性分子式:
(CH3)2PCH2P(CH3)2
化学文摘社编号:
分子量:
136.11
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.5060 (lit.)
沸点
42 °C/12 mmHg (lit.)
密度
0.86 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
CP(C)CP(C)C
InChI
1S/C5H14P2/c1-6(2)5-7(3)4/h5H2,1-4H3
InChI key
MRNJHNUEBDGNEL-UHFFFAOYSA-N
应用
Reactant for:
Catalyst for:
- Preparation of ruthenium carbonyl hydrido phosphanido diphosphine dinuclear complexes
- Luminescent face-to-face dinuclear platinum(II) alkynyl phosphine complexes
- Phosphorus-phosphorus bond and nuclear spin-spin coupling
- Formation of a catalytic ruthenium(II)-triphos complex
Catalyst for:
- Asymmetric alkylation of racemic secondary phosphines
- Palladium-diphosphine catalyzed carbonylation of ethene
警示用语：
Danger
危险声明
预防措施声明
危险分类
Pyr. Liq. 1
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Sophie Vermersch et al.
Pediatric blood & cancer, 67(6), e28286-e28286 (2020-04-12)
Malignant and multicystic peritoneal mesotheliomas are extremely rare tumors in children, developing from mesothelial cells. No specific guidelines are available at this age. We performed a retrospective analysis of all identified children (< 18-year-old) treated in France from 1987 to 2017 for
Graziella Cimino-Reale et al.
Journal of hematology & oncology, 10(1), 140-140 (2017-07-19)
Understanding the molecular/cellular underpinnings of diffuse malignant peritoneal mesothelioma (DMPM), a fatal malignancy with limited therapeutic options, is of utmost importance for the fruitful management of the disease. In this context, we previously found that telomerase activity (TA), which accounts
Giovanna Li Petri et al.
British journal of cancer, 123(4), 644-656 (2020-06-05)
Expression of proton-coupled folate transporter (PCFT) is associated with survival of mesothelioma patients treated with pemetrexed, and is reduced by hypoxia, prompting studies to elucidate their correlation. Modulation of glycolytic gene expression was evaluated by PCR arrays in tumour cells
Jana Elias et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(26), 6553-6561 (2019-03-02)
A new boron-boron dehydrocoupling strategy was established, providing convenient access to some diborane(4) compounds starting from simple borane adducts under mild conditions. In contrast to the traditional pathway using a reducing reagent, the reduction from BIII to BII was paradoxically
Michelandrea De Cesare et al.
Oncotarget, 6(15), 13119-13132 (2015-05-08)
Survivin, which is highly expressed and promotes cell survival in diffuse malignant peritoneal mesothelioma (DMPM), exclusively relies on exportin 1 (XPO1/CRM1) to be shuttled into the cytoplasm and perform its anti-apoptotic function. Here, we explored the efficacy of Selective Inhibitors
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