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Merck
CN

593702

氢化铝锂 溶液

2.0 M in THF

别名:

LAH, 丙氨酸锂, 四氢铝酸锂

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关于此项目

线性分子式:
LiAlH4
化学文摘社编号:
分子量:
37.95
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
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InChI

1S/Al.Li.4H/q-1;+1;;;;

SMILES string

[Li+].[AlH4-]

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

reaction suitability

reagent type: reductant

concentration

2.0 M in THF

density

0.906 g/mL at 25 °C

storage temp.

2-30°C

Quality Level

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Application

反应物或试剂用于:
  • 由油酸制备热塑性聚酯聚酰胺
  • 锂聚合物电池
  • 宝石-二氟亚甲基衍生物的加氢脱氟
  • 不对称羟醛反应
  • 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成

LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应

Packaging

建议将 25 mL Sure/密封瓶作为一次性使用瓶。重复穿刺可能导致产品性能下降。

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

-13.0 °F - closed cup

flash_point_c

-25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Takashi Ikegami et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 804(1), 197-201 (2004-04-20)
Bisphenol A (BPA) recognition materials were synthesized by a covalent imprinting technique using BPA-dimethacrylate or BPA-diacrylate as the template monomer. Binding sites in the polymers consisted of two hydroxyl groups that are generated by reducing the ester bonds of the
Hao Yao et al.
Journal of electron microscopy, 60(6), 375-378 (2011-10-05)
A plastic bag method was developed to observe air-sensitive samples on microstructure and phase distribution without exposure to air during the holder transfer process into the transmission electron microscope (TEM). As an example, a type of lithium aluminum hydride (Li(3)AlH(6))
José M Concellón et al.
The Journal of organic chemistry, 71(17), 6420-6426 (2006-08-12)
The reaction of chiral (2R,1'S)- or (2S,1'S)-2-(1-aminoalkyl)epoxides, 1 or 2 with a variety of organolithium compounds to obtain the corresponding (alphaS,betaS)- or (alphaR,betaS)- beta-amino alcohols in enantiopure form is reported. In both cases, the opening of the oxirane ring at
Mitsuteru Numazawa et al.
Chemical & pharmaceutical bulletin, 54(4), 554-556 (2006-04-06)
Reduction of a double bond at C-1 of 1,4-dien-3-one steroids 7 and 8 with LiAl2H4 in THF or NaB2H4 in MeOH and H2O gave stereospecifically [1alpha-2H]-labeled 4-en-3-one steroids 9 and 10, respectively. When the deuterated solvents, MeO2H and 2H2O, were

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