593702
氢化铝锂 溶液
2.0 M in THF
别名:
LAH, 丙氨酸锂, 四氢铝酸锂
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关于此项目
线性分子式:
LiAlH4
化学文摘社编号:
分子量:
37.95
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
产品名称
氢化铝锂 溶液, 2.0 M in THF
InChI
1S/Al.Li.4H/q-1;+1;;;;
SMILES string
[Li+].[AlH4-]
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
reaction suitability
reagent type: reductant
concentration
2.0 M in THF
density
0.906 g/mL at 25 °C
storage temp.
2-30°C
Quality Level
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Application
反应物或试剂用于：
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
- 由油酸制备热塑性聚酯聚酰胺
- 锂聚合物电池
- 宝石-二氟亚甲基衍生物的加氢脱氟
- 不对称羟醛反应
- 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
Packaging
建议将 25 mL Sure/密封™瓶作为一次性使用瓶。重复穿刺可能导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Hideki Hashizume et al.
The Journal of antibiotics, 57(1), 52-58 (2004-03-23)
Planar structures of tripropeptins (TPPs) were elucidated by spectroscopic studies including various NMR measurements. Stereochemistry of constituent amino acids of tripropeptin C (TPPC) (3) was identified by marfey's method except hydroxyproline which was determined by studies of NMR and CD
Andreas Grubelnik et al.
Journal of separation science, 31(10), 1739-1744 (2008-05-08)
Bacterial poly(hydroxyalkanoates) (PHAs) vary in the composition of their monomeric units. Besides saturated side-chains, unsaturated ones can also be found. The latter leads to unwanted by-products (THF ester, secondary alcohols) during acidic cleavage of the polymer backbone in the conventional
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and
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