59539
(4S,5S)-2,2-二甲基-1,3-二氧戊环-4,5-二甲醇
≥97.0% (sum of enantiomers, GC)
别名:
(+)-2,3-O-亚异丙基-L-苏力糖醇, (+)-2,3-O-异亚丙基-L-苏糖醇
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关于此项目
经验公式（希尔记法）:
C7H14O4
化学文摘社编号:
分子量:
162.18
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
256-658-6
Beilstein/REAXYS Number:
1280797
MDL number:
Assay:
≥97.0% (sum of enantiomers, GC)
Form:
solid
InChI
1S/C7H14O4/c1-7(2)10-5(3-8)6(4-9)11-7/h5-6,8-9H,3-4H2,1-2H3/t5-,6-/m0/s1
InChI key
INVRLGIKFANLFP-WDSKDSINSA-N
SMILES string
CC1(C)O[C@@H](CO)[C@H](CO)O1
assay
≥97.0% (sum of enantiomers, GC)
form
solid
optical activity
[α]20/D +3.0±0.5°, c = 5% in ethanol
bp
92-94 °C/0.1 mmHg (lit.)
mp
46-50 °C
functional group
ether, hydroxyl, ketal
Quality Level
Application
(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol can be used:
- As a key intermediate for the preparation of (6Z)-cis-9S,10R-epoxy-nonadecene, a female sex pheromone of elm spanworm.
- To prepare a chiral diphosphite ligand by reacting with phosphorochloridite using excess of NEt3.
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Synthesis of chiral alkenyl epoxides: the sex pheromone of the elm spanworm Ennomus subsignaria (Hubner)(Lepidoptera: Geometridae)
MaGee DI, et al.
Tetrahedron, 67(29), 5329-5338 (2011)
Modular chiral diphosphite derived from l-tartaric acid. Applications in metal-catalyzed asymmetric reactions
Rosas-Hern'andez A, et al.
J. Mol. Catal. A: Chem., 328(1-2), 68-75 (2010)
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