597988
环丙基硼酸
别名:
Cyclopropaneboronic acid
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关于此项目
经验公式（希尔记法）:
C3H7BO2
化学文摘社编号:
分子量:
85.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
form
solid
Quality Level
mp
90-95 °C (lit.)
storage temp.
−20°C
SMILES string
OB(O)C1CC1
InChI
1S/C3H7BO2/c5-4(6)3-1-2-3/h3,5-6H,1-2H2
InChI key
WLVKDFJTYKELLQ-UHFFFAOYSA-N
Application
试剂用于
试剂用于制备
- 微波辅助铜 (II) 催化 N -环丙基化
- 镍和铜催化的 Suzuki-Miyaura 偶联反应
- Palladacycle 催化的卤代芳烃与环丙基硼酸的 Suzuki 偶联反应
- 钯催化的环丙烷 C-H 键功能化
- 钯催化脱羧偶联
- 钯催化环丙烷的配体导向氧化功能化
- 钯催化的 Suzuki 偶联反应
试剂用于制备
- Cu(OTf)2 和 Xantphos 催化芳基硼酸与芳香醛的芳基化反应合成二芳基酮
- 基于氨基噻唑吡咯烷的酒石酸二酰胺作为 TACE 抑制剂治疗炎性疾病和癌症
Cu-介导N-环丙烷化
硼酸组分，Pd(II)、Ag(I)和苯醌环境中的碳氢键烷基化研究。
Other Notes
可能含有 3-5% 环丙醇
可能含有 5-10% 硼酸
含有不定量的酸酐
signalword
Danger
hcodes
Hazard Classifications
Repr. 1B
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle
Zhang, M.; et al.
Tetrahedron, 68, 900-905 (2012)
Chaoyang Dai et al.
Bioorganic & medicinal chemistry letters, 21(10), 3172-3176 (2011-04-05)
TNF-α converting enzyme (TACE) inhibitors are promising agents to treat inflammatory disorders and cancer. We have investigated novel tartrate diamide TACE inhibitors where the tartrate core binds to zinc in a unique tridentate fashion. Incorporating (R)-2-(2-N-alkylaminothiazol-4-yl)pyrrolidines into the left hand
Microwave-assisted N-cyclopropylation of pyridinols with cyclopropyl boronic acid
Tambe, Y. B.; et al.
Synthetic Communications, 42, 1341-1348 (2012)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 597988-5G | 04061832905358 |
| 597988-25G | 04061832905341 |
| 597988-1G | 04061832644547 |