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线性分子式:
CH3CH2C(CH3)2OK
化学文摘社编号:
分子量:
126.24
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4149025
产品名称
叔戊氧基钾 溶液, technical, ~25% in toluene (T, ~1.7 M)
InChI key
ZRLVQFQTCMUIRM-UHFFFAOYSA-N
SMILES string
[K+].CCC(C)(C)[O-]
InChI
1S/C5H11O.K/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
grade
technical
concentration
~25% in toluene (T, ~1.7 M)
density
0.90 g/mL at 20 °C
Quality Level
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Disclaimer
可能结晶;可在加热到大约30°C 时重新溶解
Application
Potassium tert-pentoxide solution has been used as a base to synthesize [RuClPh(CO)(H2IMes)(PCy3)] from second-generation Grubbs metathesis catalyst, [RuCl2(=CHPh)(H2IMes)(PCy3)], (where H2IMes is 1,3-dimethyl-4,5-dihydroimidazol-2-ylidene and PCy3 is tricyclohexylphosphine) and benzyl alcohol. This complex is a solid, air-stable and highly active isomerization catalyst.
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
39.2 °F
flash_point_c
4 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
易制毒化学品(3类)
危险化学品
此项目有
Degradation of the Second?Generation Grubbs Metathesis Catalyst with Primary Alcohols and Oxygen? Isomerization and Hydrogenation Activities of Monocarbonyl Complexes.
Dinger MB
European Journal of Inorganic Chemistry, 2003(15), 2827-2833 (2003)
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