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Merck
CN

61405

乙酰丙酸甲酯

greener alternative

≥98.0%

别名:

β-乙酰丙酸甲酯, 4-酮戊酸甲酯, 乙酰丙酸甲酯, 甲基4-戊酮酸酯, 甲基4-酮戊酸酯

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关于此项目

线性分子式:
CH3COCH2CH2COOCH3
化学文摘社编号:
分子量:
130.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-846-4
Beilstein/REAXYS Number:
1754008
MDL number:
Assay:
≥98.0%
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Quality Level

assay

≥98.0%

greener alternative product characteristics

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.422

bp

193-195 °C (lit.)

density

1.051 g/mL at 20 °C (lit.)

functional group

ester, ketone

greener alternative category

SMILES string

COC(=O)CCC(C)=O

InChI

1S/C6H10O3/c1-5(7)3-4-6(8)9-2/h3-4H2,1-2H3

InChI key

UAGJVSRUFNSIHR-UHFFFAOYSA-N

General description

在甲醇中加入几滴稀硫酸,可以将葡萄糖合成乙酰丙酸甲酯。
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Application

乙酰丙酸甲酯在lewis酸甲酯(如Hf-β)存在下可进行Meerwein-Ponndorf-Verley(MPV)还原,生成4-羟基戊酸酯。


存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

161.6 °F - closed cup

flash_point_c

72 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lutz F Tietze et al.
Organic letters, 14(16), 4035-4037 (2012-08-03)
An efficient total synthesis of (+)-(R)-Pinnatolide is described. As a key step an asymmetric multicomponent domino allylation reaction of methyl levulinate is used to form the quaternary stereogenic center in a highly selective way.
Methyl-ALA-induced fluorescence in photodynamic diagnosis of basal cell carcinoma prior to Mohs micrographic surgery.
Pedro Redondo et al.
Archives of dermatology, 144(1), 115-117 (2008-01-23)
F J Eller
Journal of AOAC International, 82(3), 766-769 (1999-07-17)
Gas chromatographic fatty acid methyl ester (GC-FAME) analyses of some acid-hydrolyzed foods revealed a large peak that did not correspond to any FAME standards. The unknown peak eluted just after the C12 FAME. If the fatty acid response factor and



全球贸易项目编号

货号GTIN
61405-100ML04061832700083