61405
乙酰丙酸甲酯
≥98.0%
别名:
β-乙酰丙酸甲酯, 4-酮戊酸甲酯, 乙酰丙酸甲酯, 甲基4-戊酮酸酯, 甲基4-酮戊酸酯
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关于此项目
线性分子式:
CH3COCH2CH2COOCH3
化学文摘社编号:
分子量:
130.14
Beilstein:
1754008
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
≥98.0%
环保替代产品特性
Safer Solvents and Auxiliaries
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sustainability
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折射率
n20/D 1.422
沸点
193-195 °C (lit.)
密度
1.051 g/mL at 20 °C (lit.)
官能团
ester
ketone
环保替代产品分类
SMILES字符串
COC(=O)CCC(C)=O
InChI
1S/C6H10O3/c1-5(7)3-4-6(8)9-2/h3-4H2,1-2H3
InChI key
UAGJVSRUFNSIHR-UHFFFAOYSA-N
一般描述
在甲醇中加入几滴稀硫酸，可以将葡萄糖合成乙酰丙酸甲酯。
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应用
乙酰丙酸甲酯在lewis酸甲酯（如Hf-β）存在下可进行Meerwein-Ponndorf-Verley（MPV）还原，生成4-羟基戊酸酯。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
161.6 °F - closed cup
闪点(°C)
72 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Methyl-ALA-induced fluorescence in photodynamic diagnosis of basal cell carcinoma prior to Mohs micrographic surgery.
Pedro Redondo et al.
Archives of dermatology, 144(1), 115-117 (2008-01-23)
Lutz F Tietze et al.
Organic letters, 14(16), 4035-4037 (2012-08-03)
An efficient total synthesis of (+)-(R)-Pinnatolide is described. As a key step an asymmetric multicomponent domino allylation reaction of methyl levulinate is used to form the quaternary stereogenic center in a highly selective way.
"Investigation of the reaction kinetics of isolated Lewis acid sites in beta zeolites for the Meerwein?Ponndorf?Verley reduction of methyl levulinate to ?-valerolactone"
<BIG>Luo.YH, et al.</BIG>
J. Catal., 320, 198-207 (2014)
Jean-Paul Ortonne et al.
Experimental dermatology, 19(7), 641-647 (2010-03-06)
During treatment of actinic keratosis (AK) lesions with imiquimod sub-clinical lesions often become visible. It is, however, unclear whether these sub-clinical lesions would be detectable beforehand. The aim of this pilot study was to compare two techniques, cross polarized light
Xiaoyu Wu et al.
Carbohydrate research, 358, 37-39 (2012-07-31)
One-pot preparation of methyl levulinate (MLA) from cellulose in near-critical methanol was studied. Acids containing SO(3)H group were proven to be effective catalysts for the production of MLA from cellulose's catalytic alcoholysis. The effects of different reaction conditions, such as
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