61405
乙酰丙酸甲酯
≥98.0%
别名:
β-乙酰丙酸甲酯, 4-酮戊酸甲酯, 乙酰丙酸甲酯, 甲基4-戊酮酸酯, 甲基4-酮戊酸酯
质量水平
方案
≥98.0%
环保替代产品特性
Safer Solvents and Auxiliaries
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sustainability
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折射率
n20/D 1.422
沸点
193-195 °C (lit.)
密度
1.051 g/mL at 20 °C (lit.)
官能团
ester
ketone
环保替代产品分类
SMILES字符串
COC(=O)CCC(C)=O
InChI
1S/C6H10O3/c1-5(7)3-4-6(8)9-2/h3-4H2,1-2H3
InChI key
UAGJVSRUFNSIHR-UHFFFAOYSA-N
一般描述
在甲醇中加入几滴稀硫酸,可以将葡萄糖合成乙酰丙酸甲酯。
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应用
乙酰丙酸甲酯在lewis酸甲酯(如Hf-β)存在下可进行Meerwein-Ponndorf-Verley(MPV)还原,生成4-羟基戊酸酯。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
161.6 °F - closed cup
闪点(°C)
72 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Lutz F Tietze et al.
Organic letters, 14(16), 4035-4037 (2012-08-03)
An efficient total synthesis of (+)-(R)-Pinnatolide is described. As a key step an asymmetric multicomponent domino allylation reaction of methyl levulinate is used to form the quaternary stereogenic center in a highly selective way.
Methyl-ALA-induced fluorescence in photodynamic diagnosis of basal cell carcinoma prior to Mohs micrographic surgery.
Pedro Redondo et al.
Archives of dermatology, 144(1), 115-117 (2008-01-23)
"Investigation of the reaction kinetics of isolated Lewis acid sites in beta zeolites for the Meerwein?Ponndorf?Verley reduction of methyl levulinate to ?-valerolactone"
<BIG>Luo.YH, et al.</BIG>
J. Catal., 320, 198-207 (2014)
Failure to treat keratoderma in Papillon-Lefevre syndrome using photodynamic therapy.
Montse Fernández-Guarino et al.
European journal of dermatology : EJD, 17(5), 456-457 (2007-08-04)
F J Eller
Journal of AOAC International, 82(3), 766-769 (1999-07-17)
Gas chromatographic fatty acid methyl ester (GC-FAME) analyses of some acid-hydrolyzed foods revealed a large peak that did not correspond to any FAME standards. The unknown peak eluted just after the C12 FAME. If the fatty acid response factor and
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