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线性分子式:
(CH3)2CHOD
化学文摘社编号:
分子量:
61.10
NACRES:
NA.12
PubChem Substance ID:
UNSPSC Code:
12142201
EC Number:
223-616-3
MDL number:
Isotopic purity:
98 atom % D
Assay:
99% (CP)
Mass shift:
M+1
InChI key
KFZMGEQAYNKOFK-QYKNYGDISA-N
InChI
1S/C3H8O/c1-3(2)4/h3-4H,1-2H3/i4D
SMILES string
[2H]OC(C)C
isotopic purity
98 atom % D
assay
99% (CP)
refractive index
n20/D 1.3752 (lit.)
bp
82 °C (lit.)
mp
-90 °C (lit.)
density
0.798 g/mL at 25 °C (lit.)
mass shift
M+1
Quality Level
General description
2-丙醇-OD是同位素标记的2-丙醇类似物。
Application
2-丙二醇-OD可用作以下研究中的溶剂:
- 单线态卡宾化合物的溶剂化(solvation)时间(动力学)
- 二苯甲酮和/或丙酮羰游离基与替拉扎明(tirapazamine)的反应机理.
2-丙醇-OD可作为溶剂用于研究二苯甲酮和/或丙酮羰自由基与替拉扎明的反应机理,用于考察 DNA 损伤和修复的确切机制。此外,它还可用于监控动力学研究中卡宾化合物的溶剂化。
Packaging
这种产品可以散装供应,并可按需包装。有关定价、供货和包装的信息,请联系稳定同位素客户服务。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
53.6 °F - closed cup
flash_point_c
12.0 °C - closed cup
法规信息
危险化学品
此项目有
The dynamics of carbene solvation: an ultrafast study of p-biphenylyltrifluoromethylcarbene
Wang J, et al.
Journal of the American Chemical Society, 130(7), 2304-2313 (2008)
Xiaofeng Shi et al.
Journal of the American Chemical Society, 129(15), 4542-4550 (2007-03-27)
Ketyl radicals produced by photolysis of ketones or di-tert-butyl peroxide (DTBP) in alcohol solvents react rapidly with tirapazamine (TPZ). The acetone ketyl radical (ACOH) reacts with TPZ with an absolute second-order rate constant of (9.7 +/- 0.4) x 108 M-1
Jin Wang et al.
Journal of the American Chemical Society, 130(7), 2304-2313 (2008-01-25)
Ultrafast photolysis (lambda(ex) = 308 nm) of p-biphenylyltrifluoromethyl diazomethane (BpCN2CF3) releases singlet p-biphenylyltrifluoromethylcarbene (BpCCF3) which absorbs strongly at 385 nm in cyclohexane, immediately after the 300 fs laser pulse. The initial absorption maximum shifts to longer wavelengths in coordinating solvents
On the mechanism of reaction of radicals with tirapazamine
Shi X, et al.
Journal of the American Chemical Society, 129(15), 4542-4550 (2007)
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