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61626

三氟化硼甲醇络合物溶液

Name: 三氟化硼甲醇络合物 溶液
Brand: ALDRICH

12.5-15.5% BF₃ basis

别名:

BF₃MeOH, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol Complex

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关于此项目

线性分子式:

BF₃ · MeOH

化学文摘社编号:

373-57-9

分子量:

131.89

UNSPSC Code:

12352104

NACRES:

NA.22

PubChem Substance ID:

57651782

MDL number:

MFCD00071635

Beilstein/REAXYS Number:

3693581

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属性

Quality Level

100

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

concentration

12.5-15.5% boron trifluoride

density

0.859 g/mL at 25 °C

functional group

hydroxyl

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

说明

General description

BF₃-MeOH溶液是一种路易斯酸-碱复合物，在有机合成中用作多功能的试剂和催化剂。

Application

三氟化硼 - 甲醇络合物溶液可用于花青染料的乙酰化胺的脱保护，以形成具有游离氨基的产物。它可用于将含硫氨基磷酸酯转化为相应的磷酸甲酯

pictograms

GHS02,GHS06,GHS08,GHS05

signalword

Danger

hcodes

H225,H301 + H311,H314,H330,H370,H373

pcodes

P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

target_organs

Eyes,Central nervous system, Kidney

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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Methanolysis of phosphoramidates with boron trifluoride-methanol complex.

Ryu S

The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)

Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.

Miltsov S

Tetrahedron Letters, 44(11), 2301-2303 (2003)

Milk from dams fed an obesogenic diet combined with a high-fat/high-sugar diet induces long-term abnormal mammary gland development in the rabbit.

C Hue-Beauvais et al.

Journal of animal science, 93(4), 1641-1655 (2015-05-29)

Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.

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全球贸易项目编号

货号	GTIN
61626-500ML	04061838254092

主要文件

三氟化硼甲醇络合物溶液

12.5-15.5% BF₃ basis