61626
三氟化硼甲醇络合物 溶液
12.5-15.5% BF3 basis
别名:
BF3MeOH, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol Complex
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关于此项目
线性分子式:
BF3 · MeOH
化学文摘社编号:
分子量:
131.89
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3693581
InChI
1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
SMILES string
CO.FB(F)F
InChI key
JBXYCUKPDAAYAS-UHFFFAOYSA-N
reaction suitability
core: boron, reagent type: Lewis acid, reagent type: catalyst
concentration
12.5-15.5% boron trifluoride
density
0.859 g/mL at 25 °C
functional group
hydroxyl
Quality Level
General description
BF3-MeOH溶液是一种路易斯酸-碱复合物，在有机合成中用作多功能的试剂和催化剂。
Application
三氟化硼 - 甲醇络合物溶液可用于花青染料的乙酰化胺的脱保护，以形成具有游离氨基的产物。它可用于将含硫氨基磷酸酯转化为相应的磷酸甲酯
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1
target_organs
Eyes,Central nervous system, Kidney
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Methanolysis of phosphoramidates with boron trifluoride-methanol complex.
Ryu S
The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)
Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.
Miltsov S
Tetrahedron Letters, 44(11), 2301-2303 (2003)
C Hue-Beauvais et al.
Journal of animal science, 93(4), 1641-1655 (2015-05-29)
Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.
Leila Nejadsadeghi et al.
Molecular biology reports, 42(2), 363-372 (2014-10-01)
Plant cells often increase cold tolerance by reprogramming their genes expression which results in adjusted metabolic alternations, a process enhanced under cold acclimation. In present study, we assessed the changes of membrane fatty acid compositions along with physio-biochemical indices like
Shulin Xiang et al.
Journal of pineal research, 59(1), 60-69 (2015-04-11)
Chemotherapeutic resistance, particularly to doxorubicin (Dox), represents a major impediment to successfully treating breast cancer and is linked to elevated tumor metabolism and tumor over-expression and/or activation of various families of receptor- and non-receptor-associated tyrosine kinases. Disruption of circadian time
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