62460
硼氢化锂
≥95.0%
别名:
Lithium boron hydride, Lithium hydroborate
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关于此项目
线性分子式:
LiBH4
化学文摘社编号:
分子量:
21.78
EC 号:
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥95.0%
表单
solid
反应适用性
reagent type: reductant
环保替代产品特性
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
275 °C (dec.)
密度
0.666 g/mL at 25 °C (lit.)
环保替代产品分类
SMILES字符串
[Li+].[BH4-]
InChI
1S/BH4.Li/h1H4;/q-1;+1
InChI key
UUKMSDRCXNLYOO-UHFFFAOYSA-N
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一般描述
We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium borohydride solution is a promising material in greener energy technologies, particularly for hydrogen storage. With a high theoretical hydrogen capacity, it enables compact and efficient energy storage systems that support clean hydrogen-powered applications Click here for more information.
应用
硼氢化锂是一种常用于还原醛、酮酯、内酯和环氧化物的通用还原剂。 催化烯烃的氢硼化。也用于制备其他硼氢化物,如硼氢化铝。
其他说明
复查;酯的顺利还原 ;用 LiBH 4 /Me 3 SiCl 还原酸和其他官能团
警示用语:
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Lithium borohydride-catalyzed selective reduction of the carbonyl group of conjugated and unconjugated alkenones with borane in tetrahydrofuran.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(7), 855-856 (1994)
Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride.
Soai, Kenso and Ookawa, Atsuhiro
The Journal of Organic Chemistry, 51(21), 4000-4005 (1986)
The Preparation of Other Borohydrides by Metathetical Reactions Utilizing the Alkali Metal Borohydrides1.
Schlesinger, HI et al.
Journal of the American Chemical Society, 75(1), 209-213 (1953)
H.C. Brown et al.
The Journal of Organic Chemistry, 47, 1604-1604 (1982)
Lithium Borohydride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
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