62460
硼氢化锂
≥95.0%
别名:
Lithium boron hydride, Lithium hydroborate
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关于此项目
线性分子式:
LiBH4
化学文摘社编号:
分子量:
21.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
241-021-7
MDL number:
Assay:
≥95.0%
Form:
solid
Quality Level
assay
≥95.0%
form
solid
reaction suitability
reagent type: reductant
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
275 °C (dec.)
density
0.666 g/mL at 25 °C (lit.)
greener alternative category
SMILES string
[Li+].[BH4-]
InChI
1S/BH4.Li/h1H4;/q-1;+1
InChI key
UUKMSDRCXNLYOO-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium borohydride solution is a promising material in greener energy technologies, particularly for hydrogen storage. With a high theoretical hydrogen capacity, it enables compact and efficient energy storage systems that support clean hydrogen-powered applications Click here for more information.
Application
硼氢化锂是一种常用于还原醛、酮酯、内酯和环氧化物的通用还原剂。 催化烯烃的氢硼化。也用于制备其他硼氢化物，如硼氢化铝。
Other Notes
复查；酯的顺利还原 ；用 LiBH 4 /Me 3 SiCl 还原酸和其他官能团
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signalword
Danger
hcodes
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
supp_hazards
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react. 1
法规信息
监管及禁止进口产品
此项目有
H.C. Brown et al.
The Journal of Organic Chemistry, 47, 1604-1604 (1982)
Lithium borohydride-catalyzed selective reduction of the carbonyl group of conjugated and unconjugated alkenones with borane in tetrahydrofuran.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(7), 855-856 (1994)
A. Giannis et al.
Angewandte Chemie (International Edition in English), 101, 220-220 (1989)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 62460-5G-F | 04061832707914 |
| 62460-25G-F | 04061832707891 |