62460
硼氢化锂
≥95.0%
别名:
Lithium boron hydride, Lithium hydroborate
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关于此项目
线性分子式:
LiBH4
化学文摘社编号:
分子量:
21.78
EC 号:
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥95.0%
表单
solid
反应适用性
reagent type: reductant
环保替代产品特性
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
275 °C (dec.)
密度
0.666 g/mL at 25 °C (lit.)
环保替代产品分类
SMILES字符串
[Li+].[BH4-]
InChI
1S/BH4.Li/h1H4;/q-1;+1
InChI key
UUKMSDRCXNLYOO-UHFFFAOYSA-N
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一般描述
We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium borohydride solution is a promising material in greener energy technologies, particularly for hydrogen storage. With a high theoretical hydrogen capacity, it enables compact and efficient energy storage systems that support clean hydrogen-powered applications Click here for more information.
应用
硼氢化锂是一种常用于还原醛、酮酯、内酯和环氧化物的通用还原剂。 催化烯烃的氢硼化。也用于制备其他硼氢化物，如硼氢化铝。
其他说明
复查；酯的顺利还原 ；用 LiBH 4 /Me 3 SiCl 还原酸和其他官能团
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride.
Soai, Kenso and Ookawa, Atsuhiro
The Journal of Organic Chemistry, 51(21), 4000-4005 (1986)
Lithium borohydride-catalyzed selective reduction of the carbonyl group of conjugated and unconjugated alkenones with borane in tetrahydrofuran.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(7), 855-856 (1994)
A. Giannis et al.
Angewandte Chemie (International Edition in English), 101, 220-220 (1989)
LiBH 4-promoted hydroboration of alkenes with 1, 3, 2-benzodioxaborole.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(4), 205-206 (1991)
The Preparation of Other Borohydrides by Metathetical Reactions Utilizing the Alkali Metal Borohydrides1.
Schlesinger, HI et al.
Journal of the American Chemical Society, 75(1), 209-213 (1953)
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