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线性分子式:
NaBH4
化学文摘社编号:
分子量:
37.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
241-004-4
MDL number:
Form:
powder
InChI
1S/BH4.Na/h1H4;/q-1;+1
InChI key
YOQDYZUWIQVZSF-UHFFFAOYSA-N
SMILES string
[BH4-].[Na+]
form
powder
reaction suitability
reagent type: reductant
mp
>300 °C (dec.) (lit.)
Quality Level
Application
VenPure® SF (Sodium borohydride powder) is a mild reducing agent used in the reduction of aldehydes and ketones to their corresponding alcohols. It is generally inert to other functional groups such as epoxides, esters, nitriles and lactones. Along with carboxylic acid, it forms acyloxyborohydride, which is a versatile reducing agent to reduce indoles, quinolones, imines, enamines, oximes and enamides.
Legal Information
VenPure is a registered trademark of Ascensus Specialties LLC
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Sodium borohydride.
Banfi L, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis., 1-13 (2014)
Sodium borohydride in carboxylic acid media: a phenomenal reduction system.
Gribble G W
Chemical Society Reviews, 27(6), 395-404 (1998)
Forty years of hydride reductions.
Brown H C and Krishnamurthy S
Tetrahedron, 35(5), 567-607 (1979)
Qinghua Cui et al.
Analytica chimica acta, 724, 86-91 (2012-04-10)
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Aldwin Suryo Rahmanto et al.
Free radical biology & medicine, 53(6), 1308-1316 (2012-08-14)
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