产品名称
吡啶-4-硼酸, 90%
InChI
1S/C5H6BNO2/c8-6(9)5-1-3-7-4-2-5/h1-4,8-9H
SMILES string
OB(O)c1ccncc1
InChI key
QLULGIRFKAWHOJ-UHFFFAOYSA-N
assay
90%
form
solid
mp
>300 °C (lit.)
storage temp.
−20°C
Quality Level
Application
试剂用于
制备过程中使用的试剂
- 钯催化的 Suzuki-Miyaura 偶联反应
- 微波辐射下无配体钯催化的 Suzuki 偶联反应
制备过程中使用的试剂
- HIV-1 蛋白酶抑制剂
- 潜在的癌症治疗药物，如 PDK1 和蛋白激酶 CK2 抑制剂
General description
4-吡啶硼酸常用作交叉偶联反应（如Suzuki-Miyaura交叉偶联）中的试剂。
Other Notes
含不定量的酸酐
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Jorge Cruz-Huerta et al.
Chemical communications (Cambridge, England), 48(35), 4241-4243 (2012-03-23)
The combination of two heteroaromatic boronic acids with pentaerythritol gave self-complementary tectons which were suitable for the generation of 2D and 3D molecular networks.
One-pot approach to N-quinolyl 3?/4?-biaryl carboxamides by microwave-assisted Suzuki--Miyaura coupling and N-boc deprotection
ZY Huang, et al.
The Journal of Organic Chemistry, 81, 9647-9657 (2016)
Ligand-free, PdCl2(PPh3)2-catalyzed, microwave-assisted Suzuki coupling of 1-chloro-3-phenylisoquinoline in the synthesis of diversified 1,3-disubstituted isoquinolines
Prabakaran, K.; Nawaz Khan, F.; Jin, J. S.
Research on Chemical Intermediates, 38, 337-346 (2012)
Sumin Lee et al.
Organic letters, 14(9), 2238-2241 (2012-04-28)
The kinetic process of key intermediates involved in the electrochemical ring opening of photochromic dithienylcyclopentenes (DTEs) has been observed for the first time, where the electronic nature of the DTEs is an important factor that determines the rate-determining step in
Jin-Tao Yu et al.
Organic & biomolecular chemistry, 10(7), 1359-1364 (2011-12-20)
An efficient palladium-catalyzed Suzuki-Miyaura coupling method involving the reaction between CTV-Br(3) and a variety of aryl and heteroaryl boronic acids in the presence of indolyl phosphane ligands has been developed. This reaction procedure provided a series of C(3)-symmetric aryl-extended rigid
商品
Suzuki-Miyaura cross-coupling reaction is extensively used in organic chemistry, polymer science, and pharmaceutical industries.
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