63670
(±)-薄荷醇
racemic, ≥98.0% (GC)
别名:
薄荷醇, 外消旋薄荷醇, 2-异丙基-5-甲基环己醇, 六氢百里香酚
蒸汽压
0.8 mmHg ( 20 °C)
质量水平
方案
≥98.0% (GC)
表单
solid
质量
racemic
沸点
216 °C (lit.)
mp
34-36 °C (lit.)
密度
0.89 g/mL at 25 °C (lit.)
官能团
hydroxyl
SMILES字符串
CC(C)C1CCC(C)CC1O
InChI
1S/C10H20O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-11H,4-6H2,1-3H3
InChI key
NOOLISFMXDJSKH-UHFFFAOYSA-N
基因信息
human ... TRPA1(8989), TRPM8(79054)
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一般描述
(±)-薄荷醇（外消旋薄荷醇）可以通过柠檬醛的氢化反应进行合成。
应用
使用皱褶假丝酵母Candida rugosa脂肪酶（CRL）和脂肪酶PS（来自洋葱假单胞菌Pseudomonas cepacia）作为催化剂，可以将(±)-薄荷醇（外消旋薄荷醇）转化为(-)-乙酸薄荷酯。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
204.8 °F
闪点(°C)
96 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
"Design, scale up and safe piloting of thymol hydrogenation and menthol racemisation"
Dudas J and Hanika J
Chemical Engineering Research and Design, 87(01), 83-90 (2009)
"Lipase-catalyzed resolution of p-menthan-3-ols monoterpenes: preparation of the enantiomer-enriched forms of menthol, isopulegol, trans-and cis-piperitol, and cis-isopiperitenol"
Serra S, et al.
Tetrahedron Asymmetry, 14(21), 3313-3319 (2003)
Brandon J Henderson et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 36(10), 2957-2974 (2016-03-11)
Upregulation of β2 subunit-containing (β2*) nicotinic acetylcholine receptors (nAChRs) is implicated in several aspects of nicotine addiction, and menthol cigarette smokers tend to upregulate β2* nAChRs more than nonmenthol cigarette smokers. We investigated the effect of long-term menthol alone on
Joanne D'Silva et al.
American journal of preventive medicine, 43(5 Suppl 3), S242-S248 (2012-10-25)
Menthol cigarettes account for 25% of the market in the U.S. The Food and Drug Administration currently is considering regulatory action on tobacco products, including a ban on menthol cigarettes. With 39% of menthol smokers reporting that they would quit
Andrew A Strasser et al.
Cancer epidemiology, biomarkers & prevention : a publication of the American Association for Cancer Research, cosponsored by the American Society of Preventive Oncology, 22(3), 382-389 (2013-01-22)
As part of the Family Smoking Prevention and Tobacco Control Act, the U.S. Food and Drug Administration charged the Tobacco Products Scientific Advisory Committee with developing a report and recommendations about the effect of menthol in cigarettes on the public
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