64296
三甲基硅基甲烷磺酸酯
≥97%
别名:
Methanesulfonic acid trimethylsilyl ester, Trimethylsilyl mesylate
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关于此项目
线性分子式:
H3CSO3OSi(CH3)3
化学文摘社编号:
分子量:
168.29
Beilstein:
2076698
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥97%
表单
liquid
折射率
n20/D 1.422 (lit.)
n20/D 1.422
沸点
103-104 °C/25 mmHg (lit.)
密度
1.09 g/mL at 25 °C (lit.)
官能团
sulfonic acid
SMILES字符串
C[Si](C)(C)OS(C)(=O)=O
InChI
1S/C4H12O3SSi/c1-8(5,6)7-9(2,3)4/h1-4H3
InChI key
BCHASIUOFGDRIO-UHFFFAOYSA-N
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应用
Reactant or reagent involved in:
- Reduction of esters to ethers using boron difluoride triflate etherate
- Elimination of C(8)-functional groups via regioselective dehydration
- Dealkylsilylation of alumazene derivatives
其他说明
硅烷化试剂
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
H.H. Hergott et al.
Liebigs Ann. Chem., 1718-1718 (1980)
J G Jun et al.
Carbohydrate research, 163(2), 247-261 (1987-06-15)
Several per-O-methylated D-glucans and D-fructans were used as models in an attempt to identify new catalysts for carrying out reductive cleavage. Included in these model studies were several D-glucans that contained 4-linked D-glucopyranosyl residues as well as one having a
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