64296
三甲基硅基甲烷磺酸酯
≥97%
别名:
Methanesulfonic acid trimethylsilyl ester, Trimethylsilyl mesylate
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关于此项目
线性分子式:
H3CSO3OSi(CH3)3
化学文摘社编号:
分子量:
168.29
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-220-2
Beilstein/REAXYS Number:
2076698
MDL number:
Assay:
≥97%
Form:
liquid
InChI key
BCHASIUOFGDRIO-UHFFFAOYSA-N
InChI
1S/C4H12O3SSi/c1-8(5,6)7-9(2,3)4/h1-4H3
SMILES string
C[Si](C)(C)OS(C)(=O)=O
assay
≥97%
form
liquid
Quality Level
bp
103-104 °C/25 mmHg (lit.)
density
1.09 g/mL at 25 °C (lit.)
functional group
sulfonic acid
Application
Reactant or reagent involved in:
- Reduction of esters to ethers using boron difluoride triflate etherate
- Elimination of C(8)-functional groups via regioselective dehydration
- Dealkylsilylation of alumazene derivatives
Other Notes
硅烷化试剂
J G Jun et al.
Carbohydrate research, 163(2), 247-261 (1987-06-15)
Several per-O-methylated D-glucans and D-fructans were used as models in an attempt to identify new catalysts for carrying out reductive cleavage. Included in these model studies were several D-glucans that contained 4-linked D-glucopyranosyl residues as well as one having a
H.H. Hergott et al.
Liebigs Ann. Chem., 1718-1718 (1980)
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