647640
氯化锆(IV)
powder, 99.99% trace metals basis
别名:
四氯化锆, 氯化锆
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关于此项目
线性分子式:
ZrCl4
化学文摘社编号:
分子量:
233.04
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
anhydrous
蒸汽压
1 mmHg ( 190 °C)
方案
99.99% trace metals basis
表单
powder
反应适用性
core: zirconium
reagent type: catalyst
转变温度
sublimation point 331 °C
密度
2.8 g/mL at 25 °C (lit.)
应用
electroplating
material synthesis precursor
SMILES字符串
Cl[Zr](Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
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一般描述
氯化锆(IV) (ZrCl4)是一种路易斯酸催化剂，毒性低。它是一种防潮材料，在有机转化中用作催化剂。
应用
ZrCl4 可作为各种有机合成的催化剂，如Friedel-Crafts反应、缩合反应和其他还原反应。
警示用语：
Danger
危险声明
危险分类
Met. Corr. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Synthesis of 2, 3-dihydroquinazolin-4 (1H)-ones catalyzed by zirconium (IV) chloride as a mild and efficient catalyst
Abdollahi-Alibeik M and Shabani E
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(10), 1163-1166 (2011)
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
Harish Kumar et al.
Ultrasonics sonochemistry, 15(2), 129-132 (2007-04-17)
Sonication of aromatic aldehydes, urea and ethyl acetoacetate in presence of solvent (ethyl alcohol) or solvent-less dry media (bentonite clay) supported-zirconium (IV) chloride (ZrCl(4)) as catalyst at 35 kHz gives 6-methyl-4-substitutedphenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid ethyl esters proficiently in high yields.
Stefania Fioravanti et al.
Organic & biomolecular chemistry, 10(41), 8207-8210 (2012-09-26)
ZrCl(4) was found to be an ideal catalyst to promote aza-Henry reactions between trifluoromethyl aldimines and some nitro alkanes giving new fluorinated β-nitro amines. The reaction is strongly influenced by the CF(3) group, the yield by the alkyl chain of
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