647640
氯化锆(IV)
powder, 99.99% trace metals basis
别名:
四氯化锆, 氯化锆
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关于此项目
线性分子式:
ZrCl4
化学文摘社编号:
分子量:
233.04
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
anhydrous
质量水平
蒸汽压
1 mmHg ( 190 °C)
方案
99.99% trace metals basis
表单
powder
反应适用性
core: zirconium
reagent type: catalyst
环保替代产品特性
Catalysis
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sustainability
Greener Alternative Product
转变温度
sublimation point 331 °C
密度
2.8 g/mL at 25 °C (lit.)
应用
electroplating
material synthesis precursor
环保替代产品分类
SMILES字符串
Cl[Zr](Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
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一般描述
氯化锆(IV) (ZrCl4)是一种路易斯酸催化剂，毒性低。它是一种防潮材料，在有机转化中用作催化剂。
应用
ZrCl4 可作为各种有机合成的催化剂，如Friedel-Crafts反应、缩合反应和其他还原反应。
特点和优势
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
警示用语：
Danger
危险声明
危险分类
Met. Corr. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Synthesis of 2, 3-dihydroquinazolin-4 (1H)-ones catalyzed by zirconium (IV) chloride as a mild and efficient catalyst
Abdollahi-Alibeik M and Shabani E
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(10), 1163-1166 (2011)
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
E Vassileva et al.
Fresenius' journal of analytical chemistry, 370(1), 52-59 (2001-06-08)
A flow-injection analysis (FIA) system incorporating a micro-column of ZrO2 has been used for the development of an on-line multi-element method for the simultaneous preconcentration and determination of Al, Bi, Cd, Co, Cr, Cu, Fe, Ga, In, Mn, Mo, Ni
A Z El-Sonbati et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(7), 1411-1424 (2002-06-27)
Some binary and ternary novel complexes of dioxouranium(VI) with 5-vinylsalicylaldehyde (VSH) have been prepared and characterized by various physico-chemical techniques. The amine exchange reactions of coordinated poly-Schiff bases in these complexes have been also carried out which give symmetrical tetradentate
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