649066
氯双环戊基膦
97%
别名:
Dicyclopentylchlorophosphine, Dicyclopentylphosphine chloride
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关于此项目
经验公式（希尔记法）:
C10H18ClP
化学文摘社编号:
分子量:
204.68
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
产品名称
氯双环戊基膦, 97%
InChI
1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
SMILES string
ClP(C1CCCC1)C2CCCC2
InChI key
QTYRJBRBODDGCQ-UHFFFAOYSA-N
assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
density
1.069 g/mL at 25 °C (lit.)
functional group
phosphine
Quality Level
Application
Chlorodicyclopentylphosphine may be used to prepare:
- Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
- (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
- LcPeNiCl, a precursor for preparing LcPeNiH, which is an efficient catalyst for the reduction of CO2[cPe=cyclopentyl]
General description
Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
New diphosphinite ligands derived from mannitol for rhodium catalyzed enantioselective hydrogenation of ketones.
Naili S, et al.
Tetrahedron Letters, 41(16), 2867-2870 (2000)
Catalytic properties of nickel bis (phosphinite) pincer complexes in the reduction of CO 2 to methanol derivatives.
Chakraborty S, et al.
Polyhedron, 32(1), 30-34 (2012)
Amidophosphine-Phosphinites: Synthesis and Use in Rhodium-Based Asymmetric Hydrogenation of Activated Keto Compounds. Crystal Structure of Bis [(?-chloro)((S)-2-((diphenylphosphino) oxy)-2-phenyl-N-(diphenylphosphino)-N-methylacetamide) rhodium (I)].
Roucoux A, et al.
Organometallics, 15(10), 2440-2449 (1996)
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