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Merck
CN

649813

PEDOT

tetramethacrylate end-capped solution, 0.5 wt. % (dispersion in propylene carbonate), contains p-toluenesulfonate as dopant

别名:

Oligotron™ PC, PEDOT, 四甲基丙烯酸酯封端的 PEDOT

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化学文摘社编号:
126213-51-2
UNSPSC Code:
12352103
NACRES:
NA.23
EC Number:
203-572-1
MDL number:
MFCD06798809

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产品名称

四甲基丙烯酸酯封端的聚乙撑二氧噻吩 溶液, 0.5 wt. % (dispersion in propylene carbonate), contains p-toluenesulfonate as dopant

mol wt

~1,360-1,600 g/mol (methacrylate equivalent weight)
average Mn ~6,000(lit.)

contains

p-toluenesulfonate as dopant

composition

Oligotron™ tetramethacrylate, 0.5 wt. %
propylene carbonate, 99.5 wt. %

concentration

0.5 wt. % (dispersion in propylene carbonate)

resistance

1-10 M Ω/sq (typical surface resistance of film)

conductivity

0.1-0.5 S/cm (bulk)

density

1.189 g/mL at 25 °C

Quality Level

100

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相关类别

Application

使用前搅拌 20 分钟可获得最佳的性能。由碳酸丙烯酯铸膜需要加热干燥。通过添加丙烯酸酯单体和光引发剂（如 DMPA）可制备光固化油墨。碳酸丙烯酯会残留在聚合物中。功能性化合物可以通过与甲基丙烯酸酯基团反应偶联至低聚物。
PEDOT-Meth can be used as a plasticizing membrane in the fabrication of ion-selective sensors and light emitting diodes.
Product can be blended with additional acrylate or methacrylate monomers and crosslinked to make polymer blends. Custom molecules can be synthesized by bonding functional compounds, via the methacrylate groups, to the conducting EDOT oligomers.

Disclaimer

请在室温下保存本品（切勿冷冻或冷藏）。如果产品出现少许沉淀，属于正常现象。使用前，请搅拌、超声并过滤。可在移液管前端填充玻璃棉，用于简易过滤。未按照要求保存本品，将严重缩短本品的保质期。如果产品发生严重的聚合反应，或如果产品经超声/过滤后仍无法达到良好的铸膜溶液条件，则不应继续使用。

Features and Benefits

封端结构使得导电低聚物 PEDOT 可分散。甲基丙烯酸酯基团为交联或进一步化学修饰提供可能。通过甲基丙烯酸酯官能团完全干燥的 Oligotron(TM) 四甲基丙烯酸酯。

General description

请单击此链接查阅 Aedotron/Oligotron 选择指南表。
Poly(3,4-ethylenedioxythiophene), tetramethacrylate end-capped solution (PEDOT-Meth) is a semiconductor based polymer that is functionalized with tetramethacrylate that facilitates effective crosslinking of the conjugated films.
The main characteristic of Oligotron™ PC is that it behaves as a reactive oligomer in non-volatile solvent. Used blended with monomers, or for reactions with functional compounds.

Legal Information

Oligotron is a trademark of TDA Research, Inc.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 2

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR5731
MKCG8740
MKCB8877
MKBV8987V
MKBP4342V

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Composite Polyacrylate- Poly (3, 4-ethylenedioxythiophene) Membranes for Improved All-Solid-State Ion-Selective Sensors
Rzewuska A, et al.
Analytical Chemistry, 80(1), 321-327 (2008)
Synthesis of water-free PEDOT with polyvinylpyrrolidone stabilizer in organic dispersant system
He J, et al.
Organic Electronics, 53, 117-126 (2018)
Cristina Ocaña et al.
Talanta, 186, 279-285 (2018-05-23)
We report here the fabrication of solid-contact calcium-selective electrodes (Ca2+-SCISEs) made of a polyurethane acrylate ion-selective membrane (ISM) that was covalently attached to the underlying ion-to-electron transducer (solid-contact). Methacrylate-functionalized poly(3,4-ethylenedioxythiophene) (Meth-PEDOT) and Meth-PEDOT films containing either multiwalled carbon nanotubes (MWCNT)

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Flexible and Printed Organic Thermoelectrics: Opportunities and Challenges

Progress in Organic Thermoelectric Materials & Devices including high ZT values of >0.2 at room temperature by p-type (PEDOT:PSS) & n-type (Poly[Kx(Ni-ett)]) materials are discussed.

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