650412
硼烷四氢呋喃络合物 溶液
1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer
别名:
Borane-THF (1:1), Borane-THF complex (1:1)
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关于此项目
线性分子式:
BH3OC4H8
化学文摘社编号:
分子量:
85.94
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
3668402
MDL number:
产品名称
硼烷四氢呋喃络合物 溶液, 1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer
SMILES string
B.C1CCOC1
InChI
1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3
InChI key
RMCYTHFAWCWRFA-UHFFFAOYSA-N
contains
0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.880 g/mL at 25 °C
functional group
ether
storage temp.
2-8°C
Quality Level
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Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Hisanori Ueki et al.
The Journal of organic chemistry, 71(9), 3506-3511 (2006-04-22)
This paper presents a highly stereoselective synthesis of trifluoro- or difluoromethylated olefins via an S(N)2' type fluorination or reductions of gem-difluorinated vinyloxiranes. Their fluorination with HF-Py furnished trifluoromethylated allylic alcohols with exclusive E selectivity. On the other hand, their reduction
Polymer, 47, 4916-4916 (2006)
Jung Seok Lee et al.
Macromolecular bioscience, 15(9), 1314-1322 (2015-06-04)
We designed poly(β-amino esters) (PBAEs) bearing both UV light- and pH-sensitive groups and used PBAEs to prepare nanoparticles (NPs) that can be utilized for on-demand burst release of guest molecules in response to multiple triggers. Due to the presence of
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