658243
吡咯烷并硼氢化锂 溶液
1 M in THF
别名:
三氢-1-吡咯烷基硼酸锂
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关于此项目
经验公式（希尔记法）:
C4H11BLiN
化学文摘社编号:
分子量:
90.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
reaction suitability
reagent type: reductant
concentration
1 M in THF
refractive index
n20/D 1.425
density
0.890 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li+].[H][B-]([H])([H])N1CCCC1
InChI
1S/C4H11BN.Li/c5-6-3-1-2-4-6;/h1-4H2,5H3;/q-1;+1
InChI key
CUBZYJJJUFGOBJ-UHFFFAOYSA-N
Application
能够还原各种官能团。
在与卤代吡啶类化合物和伯烷基甲磺酸酯类化合物反应的情况下，LAB 可以转移胺部分。
Lithium Aminoborohydride (LAB) Reagents
- Reducing agent for reduction of carbonic and carboxylic acid derivatives
- Reagent for reduction-amination reactions
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17.0 °C - closed cup
法规信息
危险化学品
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商品
Lithium aminoborohydride (LAB) reagents are a new class of powerful and selective reagents developed in the laboratory of Professor Bakthan Singaram at the University of California, Santa Cruz.
相关内容
New asymmetric methodology meets the continuous demand for optically active compounds in various fields.
Saikia, P.P.
Synlett, 995-995 (2007)
Fisher, G. B. et al
The Journal of Organic Chemistry, 59, 6378-6378 (1994)
Pasumansky, L. et al
Aldrichimica Acta, 38, 61-61 (2005)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 658243-100ML | 04061838136169 |
| 658243-25ML | 04061838136176 |