663085
(5S)-(-)-2,2,3-三甲基-5-苄基-4-咪唑啉酮二氯乙酸
97%
别名:
(5S)-2,2,3-三甲基-5-苯甲基-4-咪唑啉酮二氯乙酸
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C15H20Cl2N2O3
化学文摘社编号:
分子量:
347.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(5S)-(-)-2,2,3-三甲基-5-苄基-4-咪唑啉酮二氯乙酸, 97%
InChI
1S/C13H18N2O.C2H2Cl2O2/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;3-1(4)2(5)6/h4-8,11,14H,9H2,1-3H3;1H,(H,5,6)/t11-;/m0./s1
SMILES string
OC(=O)C(Cl)Cl.CN1C(=O)[C@H](Cc2ccccc2)NC1(C)C
InChI key
YZRAPAXOLQHZSE-MERQFXBCSA-N
assay
97%
mp
122-126 °C
functional group
carboxylic acid
chloro
phenyl
Quality Level
Application
用于首例有机催化的醛对映选择性 α-氟化。
Legal Information
适用美国专利6,369,243 和相关专利。仅供研究使用。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Teresa D Beeson et al.
Journal of the American Chemical Society, 127(24), 8826-8828 (2005-06-16)
The first direct enantioselective catalytic alpha-fluorination of aldehydes has been accomplished. The use of enamine catalysis has provided a new organocatalytic strategy for the enantioselective fluorination of aldehydes to generate alpha-fluoro aldehydes, an important chiral synthon for medicinal agent synthesis.
商品
Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持