663212
异丙烯基硼酸频哪醇酯
contains BHT as stabilizer, 94.5%
别名:
2-异丙烯基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷
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关于此项目
经验公式（希尔记法）:
C9H17BO2
化学文摘社编号:
分子量:
168.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C9H17BO2/c1-7(2)10-11-8(3,4)9(5,6)12-10/h1H2,2-6H3
SMILES string
CC(=C)B1OC(C)(C)C(C)(C)O1
InChI key
SVSUYEJKNSMKKW-UHFFFAOYSA-N
assay
94.5%
contains
BHT as stabilizer
refractive index
n20/D 1.4320
bp
47-49 °C/9 mbar
density
0.894 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
Reagent used for
Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
- Palladium-catalyzed Suzuki-Miyaura cross-coupling processes
- Inverse-electron-demand Diels-Alder reaction
- Simmons-Smith Cyclopropanation Reaction
- Polyene cyclization
- Stereoselective aldol reactions
- Grubbs cross-metathesis reaction
- Intramolecular Suzuki-Miyaura reaction
- Stereoselective cross-metathesis
- Dipolar cycloaddition
- Iodosulfonylation
- Asymmetric conjugate addition and intramolecular hydroacylation
Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
Reagent used for
Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
- Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions
- Inverse-electron-demand Diels-Alder reaction
- Simmons-Smith Cyclopropanation Reaction
- Polyene cyclization
- Stereoselective aldol reactions
- Grubbs cross-metathesis reaction
- Intramolecular Suzuki-Miyaura reaction
- Stereoselective cross-metathesis
- Dipolar cycloaddition
- Iodosulfonylation
- Asymmetric conjugate addition and intramolecular hydroacylation
Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
signalword
Warning
Hazard Classifications
Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
107.6 °F
flash_point_c
42 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Facile Access to 3,5-Dihalogenated Pyrazoles by Sydnone Cycloaddition and their Versatile Functionalization by Pd-Catalyzed Cross-Coupling Processes
Delaunay, T.; et al.
European Journal of Organic Chemistry, 20-21, 3837-3848 (2011)
First Total Synthesis of Rhodexin A
Jung, M. E.; Yoo, D.
Organic Letters, 13, 3766-3766 (2011)
Yu-Jun Zhao et al.
Organic letters, 10(11), 2143-2145 (2008-04-29)
The first asymmetric total synthesis of antiochic acid using bioinspired polyene cyclization strategy is described. Both good yield and good asymmetric induction were obtained.
Catalytic asymmetric intramolecular hydroacylation with rhodium/phosphoramidite-alkene ligand complexes.
Thomas J Hoffman et al.
Angewandte Chemie (International ed. in English), 50(45), 10670-10674 (2011-09-20)
Simmons-Smith cyclopropanation reaction
Charette, A. B.; Beauchemin, A.
Org. React., 58 (2001)
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