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663212

异丙烯基硼酸频哪醇酯

contains BHT as stabilizer, 94.5%

别名:

2-异丙烯基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷

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关于此项目

经验公式（希尔记法）:
C9H17BO2
化学文摘社编号:
126726-62-3
分子量:
168.04
NACRES:
NA.22
PubChem Substance ID:
24884621
UNSPSC Code:
12352103
MDL number:
MFCD08276843
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Quality Level

100

assay

94.5%

contains

BHT as stabilizer

refractive index

n20/D 1.4320

bp

47-49 °C/9 mbar

density

0.894 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(=C)B1OC(C)(C)C(C)(C)O1

InChI

1S/C9H17BO2/c1-7(2)10-11-8(3,4)9(5,6)12-10/h1H2,2-6H3

InChI key

SVSUYEJKNSMKKW-UHFFFAOYSA-N

Application

Reagent used for
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling processes
  • Inverse-electron-demand Diels-Alder reaction
  • Simmons-Smith Cyclopropanation Reaction
  • Polyene cyclization
  • Stereoselective aldol reactions
  • Grubbs cross-metathesis reaction
  • Intramolecular Suzuki-Miyaura reaction
  • Stereoselective cross-metathesis
  • Dipolar cycloaddition
  • Iodosulfonylation
  • Asymmetric conjugate addition and intramolecular hydroacylation

Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
Reagent used for
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions
  • Inverse-electron-demand Diels-Alder reaction
  • Simmons-Smith Cyclopropanation Reaction
  • Polyene cyclization
  • Stereoselective aldol reactions
  • Grubbs cross-metathesis reaction
  • Intramolecular Suzuki-Miyaura reaction
  • Stereoselective cross-metathesis
  • Dipolar cycloaddition
  • Iodosulfonylation
  • Asymmetric conjugate addition and intramolecular hydroacylation

Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

107.6 °F

flash_point_c

42 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ4160
MKCQ9407
MKCP4891
SHBJ7424
SHBH5064V

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Catalytic asymmetric intramolecular hydroacylation with rhodium/phosphoramidite-alkene ligand complexes.
Thomas J Hoffman et al.
Angewandte Chemie (International ed. in English), 50(45), 10670-10674 (2011-09-20)
Simmons-Smith cyclopropanation reaction
Charette, A. B.; Beauchemin, A.
Org. React., 58 (2001)
Yu-Jun Zhao et al.
Organic letters, 10(11), 2143-2145 (2008-04-29)
The first asymmetric total synthesis of antiochic acid using bioinspired polyene cyclization strategy is described. Both good yield and good asymmetric induction were obtained.
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全球贸易项目编号

货号GTIN
663212-5G04061837894794
663212-25G04061832880792