665355
(S)-(+)-苄基(3,5-二氧杂-4-磷杂-环庚[2,1-a;3,4-a′]二萘-4-基)甲胺
97%
别名:
(+)-N-苄基-N-甲基-二萘并[2,1-d:1′,2′]二噁磷杂庚英-4-胺，(11bS)
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选择尺寸
关于此项目
经验公式（希尔记法）:
C28H22NO2P
化学文摘社编号:
分子量:
435.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S)-(+)-苄基(3,5-二氧杂-4-磷杂-环庚[2,1-a;3,4-a′]二萘-4-基)甲胺, 97%
InChI
1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3
SMILES string
CN(Cc1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56
InChI key
OHGGHRJGBXAKKY-UHFFFAOYSA-N
assay
97%
form
solid
mp
155-159 °C
Quality Level
Application
用作芳基硼酸经铑催化不对称 1,4-加成到 α,β-不饱和羰基化合物的亚磷酰胺配体。还用于N-酰化 β-脱氢氨基酯的不对称氢化，生成对映纯 β-氨基酸衍生物。
Legal Information
经 DSM 授权销售，仅供研究之用。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Diego Peña et al.
Journal of the American Chemical Society, 124(49), 14552-14553 (2002-12-06)
New and very easily accessible monodentate phosphoramidite ligands have been developed that lead to excellent ee's and full conversions in the hydrogenation of (E)- and (Z)-beta-dehydroamino acid derivatives with both aliphatic and aromatic side chains. Particularly, two different catalytic systems
Journal of Organometallic Chemistry, 692, 428-428 (2007)
商品
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