665363
(S,R,R)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)二(1-苯基乙基)胺
95% (HPLC)
别名:
(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, (11bS)
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选择尺寸
关于此项目
经验公式（希尔记法）:
C36H30NO2P
化学文摘社编号:
分子量:
539.60
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S,R,R)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)二(1-苯基乙基)胺, 95% (HPLC)
InChI key
LKZPDRCMCSBQFN-CLJLJLNGSA-N
SMILES string
C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56)c7ccccc7
InChI
1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m1/s1
assay
95% (HPLC)
mp
102-103 °C
functional group
amine
phenyl
Quality Level
Application
手性亚磷酰胺配体，用于铜催化的高对映选择性共轭加成反应，该反应可将二烷基锌加成到各种 Michael 受体。也可用于二乙基锌介导的钯催化极性反转烯丙基化反应。
Legal Information
经 DSM 授权销售，仅供研究使用。
MonoPhos is a registered trademark of DSM IP Assets B.V.
Features and Benefits
Advantages of the MonoPhos® ligands:
- Superior enantiocontrol in numerous transformations
- High activities at low catalyst loadings
- Hydrogenations under low-pressure conditions
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Organic & Biomolecular Chemistry, 4, 1278-1278 (2006)
Privileged Ligands
Aldrich Chemfiles, 6(8), 7-7 null
Jorge Esquivias et al.
The Journal of organic chemistry, 70(18), 7451-7454 (2005-08-27)
[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reagents to (2-pyridylsulfonyl)imines of chalcones. This process occurs rapidly in the presence of a chiral phosphoramidite ligand to
Oliver Knopff et al.
Organic letters, 4(22), 3835-3837 (2003-02-26)
[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, as silyl enol ethers with TMSOTf in apolar solvents or with TMSCI and NEt3.
Synlett, 1375-1375 (2001)
商品
DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.
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