667544
氯化锂 溶液
0.5 M in anhydrous tetrahydrofuran
别名:
Lithium chloride, Lithium monochloride
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关于此项目
线性分子式:
LiCl
化学文摘社编号:
分子量:
42.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
InChI
1S/ClH.Li/h1H;/q;+1/p-1
SMILES string
[Li+].[Cl-]
InChI key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
concentration
0.5 M in anhydrous tetrahydrofuran
impurities
≤50 ppm water
density
0.913 g/mL at 25 °C
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Application
氯化锂（LiCl）是亲核氯化物阴离子的来源，它可以将醇转化为氯代烷。它催化二异丙基氨基锂（LDA）介导的一系列芳烃的邻位化。LiCl 溶液也用于制备有机卤化锌。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
On-demand synthesis of organozinc halides under continuous flow conditions.
Berton, Mateo et al.
Nature Protocols, 13(1), 324-324 (2018)
Lithium Chloride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Lekha Gupta et al.
The Journal of organic chemistry, 74(5), 2231-2233 (2009-02-05)
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial accelerations by as little as 0.5 mol % of LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity
Sima Rahman et al.
PloS one, 7(12), e51746-e51746 (2012-12-29)
Lineage allocation of the marrow mesenchymal stem cells (MSCs) to osteoblasts and adipocytes is dependent on both Wnt signaling and PPARγ2 activity. Activation of PPARγ2, an essential regulator of energy metabolism and insulin sensitivity, stimulates adipocyte and suppresses osteoblast differentiation
Karla M Acevedo et al.
The Journal of biological chemistry, 289(16), 11007-11019 (2014-03-13)
Amyloid precursor protein (APP) undergoes post-translational modification, including O- and N-glycosylation, ubiquitination, and phosphorylation as it traffics through the secretory pathway. We have previously reported that copper promotes a change in the cellular localization of APP. We now report that
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