667544
氯化锂 溶液
0.5 M in anhydrous tetrahydrofuran
别名:
Lithium chloride, Lithium monochloride
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关于此项目
线性分子式:
LiCl
化学文摘社编号:
分子量:
42.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
InChI
1S/ClH.Li/h1H;/q;+1/p-1
SMILES string
[Li+].[Cl-]
InChI key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
concentration
0.5 M in anhydrous tetrahydrofuran
impurities
≤50 ppm water
density
0.913 g/mL at 25 °C
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Application
氯化锂（LiCl）是亲核氯化物阴离子的来源，它可以将醇转化为氯代烷。它催化二异丙基氨基锂（LDA）介导的一系列芳烃的邻位化。LiCl 溶液也用于制备有机卤化锌。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Lithium Chloride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
On-demand synthesis of organozinc halides under continuous flow conditions.
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The Journal of organic chemistry, 74(5), 2231-2233 (2009-02-05)
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