Quality Level
assay
97%
refractive index
n20/D 1.430
bp
189 °C/760 mmHg
density
0.841 g/mL at 25 °C
functional group
amine, ether
SMILES string
CN(C)CCOCCN(C)C
InChI
1S/C8H20N2O/c1-9(2)5-7-11-8-6-10(3)4/h5-8H2,1-4H3
InChI key
GTEXIOINCJRBIO-UHFFFAOYSA-N
General description
2-(二甲氨基)乙醚是一种三齿配体。在交换反应中,它有助于中间体的形成和稳定。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
151.0 °F
flash_point_c
66.11 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
商品
Substantial progress has been made in magnesium–halogen exchange reactions used for the preparation of functionalized Grignard reagents containing sensitive moieties such as ester or cyano groups.
Bis[2-(dimethylamino)ethyl]ether(CH3)2NCH2CH2OCH2CH2N(CH3)2.
B Ballantyne
Journal of applied toxicology : JAT, 25(3), 260-269 (2005-04-28)
Chao-Shan Da et al.
Organic letters, 11(24), 5578-5581 (2009-11-17)
Generally used and highly reactive RMgBr reagents were effectively deactivated by bis[2-(N,N-dimethylamino)ethyl] ether and then were employed in the highly enantioselective addition of Grignard reagents to aldehydes. The reaction was catalyzed by the complex of commercially available (S)-BINOL and Ti(O(i-)Pr)(4)
Mild Iodine- Magnesium Exchange of Iodoaromatics Bearing a Pyrimidine Ring with Isopropylmagnesium Chloride
Wang XJ, et al.
Organic Letters, 8, 3141-3144 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 667609-100ML | 04061832734651 |
| 667609-500ML | 04061832734668 |

