66770
亚甲基二胺 二盐酸盐
≥98.0% (AT)
别名:
二氨基甲烷 二盐酸盐
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关于此项目
线性分子式:
CH2(NH2)2 · 2HCl
化学文摘社编号:
分子量:
118.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
260-602-6
Beilstein/REAXYS Number:
3664689
MDL number:
产品名称
亚甲基二胺 二盐酸盐, ≥98.0% (AT)
InChI key
QCYJCJJCNRIMNG-UHFFFAOYSA-N
InChI
1S/CH6N2.2ClH/c2-1-3;;/h1-3H2;2*1H
SMILES string
Cl.Cl.NCN
assay
≥98.0% (AT)
form
solid
functional group
amine
storage temp.
2-8°C
Quality Level
Application
亚甲基二胺 二盐酸盐可作为以下合成反应的反应物：
- 在1-丁醇参与下与双氰酰胺钠缩聚反应生成聚亚甲基双胍
- 在碳酸氢钠参与下与(2S)-2-甲基十二烷基氯酰化生成双十二酰胺
General description
亚甲基二胺二盐酸盐，又称二氨基甲烷二盐酸盐，是一种有机化合物，常用作反应试剂和缓慢的氨释放试剂，用于通过活性酯合成肽和氨基酸的一级酰胺。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Poly(alkylene biguanides) as proton conductors for high-temperature PEMFCs.
Jochen Britz et al.
Advanced materials (Deerfield Beach, Fla.), 22(8), E72-E76 (2010-03-11)
G Galaverna et al.
International journal of peptide and protein research, 42(1), 53-57 (1993-07-01)
Amide formation from acids, N-protected amino acids and peptides was achieved in an easy and convenient way by treating "active esters" such as succinimidyl or 4-nitrophenyl esters or acyl chlorides with diaminomethane dihydrochloride in dioxane in the presence of Et3N.
Nickel-catalyzed transfer semihydrogenation and hydroamination of aromatic alkynes using amines as hydrogen donors
Reyes S, et al.
Organometallics, 30, 3340-3345 (2011)
Takaaki Sumiyoshi et al.
Journal of the American Chemical Society, 125(40), 12137-12142 (2003-10-02)
A series of 10 didodecanoylamides of alpha,omega-alkylidenediamines bridged by a straight carbon chain varying in length from 0 to 9 carbons was examined as possible gelator molecules of organic liquids to gain information on the relationships between the spacial arrangement
'Passe-partout effect' in positive patch test reactions: a novel pattern of edge effect.
Esen Ozkaya
Contact dermatitis, 61(4), 245-247 (2009-10-15)
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