667897
1,2-二乙氧基-1,1,2,2-四甲基二硅烷
97%
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关于此项目
线性分子式:
((CH3CH2O)(CH3)2Si)2
化学文摘社编号:
分子量:
206.43
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
折射率
n20/D 1.423
沸点
84 °C/50 mmHg
密度
0.836 g/mL at 25 °C
SMILES字符串
CCO[Si](C)(C)[Si](C)(C)OCC
InChI
1S/C8H22O2Si2/c1-7-9-11(3,4)12(5,6)10-8-2/h7-8H2,1-6H3
InChI key
GWIVSKPSMYHUAK-UHFFFAOYSA-N
应用
二硅烷试剂，用于制备二甲基硅醇交叉偶联配偶体。
Scott E Denmark et al.
Organic letters, 5(19), 3483-3486 (2003-09-12)
[reaction: see text] A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.
商品
Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.
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