669032
PEPPSI™-IPr 催化剂
98%, Umicore
别名:
[1,3-双(2,6-二异丙基苯基)咪唑-2-基亚基](3-氯吡啶基)二氯化钯(II)
选择尺寸
关于此项目
产品名称
PEPPSI™-IPr 催化剂, 98%, Umicore
Quality Level
assay
98%
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
manufacturer/tradename
Umicore
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
230 °C
greener alternative category
SMILES string
Cl[Pd]Cl.Clc1cccnc1.CC(C)c2cccc(C(C)C)c2N3CN(C=C3)c4c(cccc4C(C)C)C(C)C
InChI
1S/C27H38N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-16,18-21H,17H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2
InChI key
BLDKGTGQENJFON-UHFFFAOYSA-L
General description
Application
- Kumada-Tamao-Corriu（KTC） 反应的催化剂（平衡1)
- Negishi偶联反应的催化剂 (eq.2）
- Suzuki 偶联反应的催化剂（平衡3）
- Buchwald-Hartwig 胺化反应的催化剂（平衡4)
对于小规模和高通量用途，产品为ChemBeads （931063）
Legal Information
该产品及其制造或使用是Umicore PMC拥有或控制的一项或多项已授权或正在申请的美国专利（和国外等同产品）的主题。通过Sigma-Aldrich、其关联公司或其授权分销商从Umicore PMC购买该产品，将授予买方有限的、一次性、非独家、不可让渡、不可转让的许可。买方使用此产品可能会侵犯第三方拥有或控制的专利。买方的唯一责任是确保产品的使用不会侵犯第三方的专利权或超出本协议授权的许可范围。
如需更多产品相关信息，请在http://www.pmc.umicore.com上联系您当地的Umicore PMC负责人。
已获得专利，美国专利号7,250,510。由Total Synthesis Ltd独家授权销售。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
Choose Ascentis® Express Peptide ES-C18 U/HPLC Columns based on Fused-Core® technology for fast and efficient separation of high-molecular weight compounds, such as peptides and small proteins. With a 2.7 µm particle size and rigorous testing, these columns offer reliable results and high efficiency.
PEPPSI™ palladium N-heterocyclic-carbene catalyst system enhances efficiency and functional group tolerance in catalysis.
Professor Mike Organ and co-workers have developed the PEPPSI™ (Pyridine-Enhanced Precatalyst Preparation Stabilization and Initiation) precatalysts for palladium-catalyzed cross-coupling reactions.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 669032-250G | 04061833399514 |
| 669032-1G | 04061832734910 |
| 669032-5G | 04061832734927 |
| 669032-1KG | 04061826680360 |