669660
(S,S)-(+)-N,N′-二甲基-1,2-环己二胺
≥97.0% (GC)
别名:
(1S)-反式-1,2-双(甲氨基)环己烷, (S,S)-N,N′-二甲基-1,2-二氨基环己烷
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关于此项目
经验公式（希尔记法）:
C8H18N2
化学文摘社编号:
分子量:
142.24
Beilstein:
4304824
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
方案
≥97.0% (GC)
旋光性
[α]/D +145±5°, c = 4.47 in chloroform
mp
39-44 °C
官能团
amine
储存温度
2-8°C
SMILES字符串
CN[C@H]1CCCC[C@@H]1NC
InChI
1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m0/s1
InChI key
JRHPOFJADXHYBR-YUMQZZPRSA-N
应用
(S,S)-(+)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:
- To synthesize derivatives of α-diazophosphonic acid, which are employed in O-H and N-H insertion reactions.
- As a starting material for the synthesis of α-chloro-α-alkylphosphonic acids.
- To prepare C2 symmetrical diamine enantiomers of C60 with chirospectrosopic properties.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
165.2 °F - closed cup
闪点(°C)
74 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Synthesis and characterization of both enantiomers of a chiral C60 derivative with C2 symmetry
Maggini M, et al.
Tetrahedron Letters, 36(16), 2845-2846 (1995)
Preparation of chiral α-diazophosphonic acid derivatives
Moody CJ, et al.
Tetrahedron Asymmetry, 12(11), 1657-1661 (2001)
(3a R, 7a R)-2-Ethyloctahydro-1 H-1, 3-dineopentyl-1, 3, 2-benzodiazaphosphole Oxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 12(11), 1657-1661 (2001)
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