(S)-α,α-双(3,5-二甲苯基)-2-吡咯烷甲醇

Name: (<I>S</I>)-α,α-双(3,5-二甲苯基)-2-吡咯烷甲醇
Brand: ALDRICH

≥99% (HPLC)

别名:

(S)-(-)-2-[双(3,5-二甲苯基)羟甲基]吡咯烷

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关于此项目

经验公式（希尔记法）:

C₂₁H₂₇NO

化学文摘社编号:

131180-63-7

分子量:

309.45

NACRES:

NA.22

PubChem Substance ID:

329760383

UNSPSC Code:

12352005

MDL number:

MFCD10566962

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产品名称

(S)-α,α-双(3,5-二甲苯基)-2-吡咯烷甲醇, ≥99% (HPLC)

InChI

1S/C21H27NO/c1-14-8-15(2)11-18(10-14)21(23,20-6-5-7-22-20)19-12-16(3)9-17(4)13-19/h8-13,20,22-23H,5-7H2,1-4H3/t20-/m0/s1

SMILES string

Cc1cc(C)cc(c1)C(O)([C@@H]2CCCN2)c3cc(C)cc(C)c3

InChI key

MXIOBZPVLNQGIU-FQEVSTJZSA-N

assay

≥99% (HPLC)

optical purity

enantiomeric ratio: 97.5% (HPLC)

mp

98-101 °C

functional group

hydroxyl

storage temp.

2-8°C

Quality Level

200

Application

(S)-α,α-Bis(3,5-dimethylphenyl)-2-pyrrolidinemethanol can be used as:

A chiral organocatalyst in the preparation of α-[(phenyl)methyl]thio]alkanal derivatives using aldehydes as starting materials and [(phenyl)methyl]thio]triazole as a sulfur electrophile.
A catalyst in the preparation of chiral bipyrazolidin-3-one derivatives by cycloadditions of azomethine imines with α,β-unsaturated aldehydes.