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关于此项目
经验公式(希尔记法):
C7H15N2O4P
化学文摘社编号:
分子量:
222.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Application
1,3-Dimethylimidazolium dimethyl phosphate ([MMIM][DMP]) can be used as a catalyst and a solvent for the preparation of ethyl 2-cyano-3-phenylpropenoate from benzaldehyde and ethyl cyanoacetate via Knoevenagel condensation. It can also be used to produce bioethanol from sugarcane bagasse by enzymatic hydrolysis.
General description
1,3-Dimethylimidazolium dimethyl phosphate is an imidazolium-based phosphoric ionic liquid that can be prepared by reacting 1-methylimidazole with trimethyl phosphate. The pretreatment of sugarcane bagasse with [MMIM][DMP] yields glucose and xylose via enzymatic saccharification.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Extractive desulfurization of gasoline using imidazolium-based phosphoric ionic liquids.
Nie Y, et al.
Energy and Fuels, 20(5), 2083-2087 (2006)
Imidazolium dialkylphosphates-a class of versatile, halogen-free and hydrolytically stable ionic liquids.
Kuhlmann E, et al.
Green Chemistry, 9(3), 233-242 (2007)
Dialkylimidazolium dimethyl phosphates as solvents and catalysts for the Knoevenagel condensation reaction.
Zicmanis A and Anteina L.
Tetrahedron Letters, 55(12), 2027-2028 (2014)
Samaneh Bahrani et al.
Bioresource technology, 185, 411-415 (2015-03-26)
In this study, an imidazolium-based ionic liquid (IL), 1,3-dimethylimidazolium dimethyl phosphate ([Mmim][DMP]), was applied for pretreating sugarcane bagasse to produce bioethanol. The main goal of this study was to investigate the feasibility of bagasse pretreatment with this IL, and to
Major improvement in the rate and yield of enzymatic saccharification of sugarcane bagasse via pretreatment with the ionic liquid 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]).
da Silva ASA, et al.
Bioresource Technology, 102(22), 10505-10509 (2011)
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