673854
4-硝基苯硼酸
≥95.0%
别名:
4-Nitrobenzeneboronic acid, p-Nitrophenylboronic acid, p-nitro-benzeneboronic acid
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关于此项目
线性分子式:
(O2N)C6H4(B(OH)2)
化学文摘社编号:
分子量:
166.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
4-硝基苯硼酸, ≥95.0%
InChI
1S/C6H6BNO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,9-10H
SMILES string
OB(O)c1ccc(cc1)[N+]([O-])=O
InChI key
NSFJAFZHYOAMHL-UHFFFAOYSA-N
assay
≥95.0%
form
solid
mp
285-290 °C (dec.)
functional group
nitro
Quality Level
Application
试剂用于
试剂用于制备
- 无配体的钯催化Suzuki-Miyaura交叉偶联反应
- 钌催化的无环胺苄基sp3 碳的直接芳基化
- Diels-Alder或C-H活化反应
- 区域选择性Suzuki-Miyaura偶联和串联钯催化的分子内氨基羰基化和环化反应
- 乙酰丙酮铜催化的苯脲的N-芳基化反应
- 通过双芳基化过程实现的环保型一锅合成法
- 铜介导的氰化反应
- 铜催化的芳基化反应
- 区域选择性糖基化反应
- Suzuki偶联反应及随后的芳基化反应
- 铑接枝水滑石催化剂的X射线吸收，用于有机硼试剂对缺电子烯烃的非均相1,4-加成反应
试剂用于制备
- 康普瑞汀类似物，作为潜在的抗肿瘤剂
- 人类免疫缺陷病毒（HIV）蛋白酶抑制剂，对耐药病毒具有抗病毒活性
Other Notes
可能含不定量的酸酐
David A Degoey et al.
Journal of medicinal chemistry, 54(20), 7094-7104 (2011-09-09)
Because there is currently no cure for HIV infection, patients must remain on long-term drug therapy, leading to concerns over potential drug side effects and the emergence of drug resistance. For this reason, new and safe antiretroviral agents with improved
Rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins
Motokura, K.; et al.
Green Chemistry, 13, 2416-2422 (2011)
Copper-catalyzed arylation of indolin-2,3-ones with arylboronic acids
J. Zhang, et al.,
Tetrahedron, 67, 9347-9351 (2011)
Abdallah Hamze et al.
ChemMedChem, 6(12), 2179-2191 (2011-10-13)
A novel class of isocombretastatin A-4 (isoCA-4) analogues with modifications at the 3'-position of the B-ring by replacement with C-linked substituents was studied. Exploration of the structure-activity relationships of theses analogues led to the identification of several compounds that exhibit
Tetrahedron, 63, 6131-6131 (2007)
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