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Merck
CN

674583

高氯酸银

97%

别名:

Perchloric acid silver(1+) salt, Silver(1+) perchlorate

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关于此项目

线性分子式:
AgClO4
化学文摘社编号:
7783-93-9
分子量:
207.32
NACRES:
NA.23
PubChem Substance ID:
24885223
UNSPSC Code:
12352302
EC Number:
232-035-4
MDL number:
MFCD00003400
Assay:
97%
Grade:
anhydrous
Form:
solid
Solubility:
benzene: slightly soluble(lit.), pyridine: slightly soluble(lit.)

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InChI key

YDHABVNRCBNRNZ-UHFFFAOYSA-M

InChI

1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1

SMILES string

[Ag+].[O-]Cl(=O)(=O)=O

grade

anhydrous

assay

97%

form

solid

reaction suitability

core: silver, reagent type: catalyst

impurities

≤0.1% Insoluble matter

mp

486 °C (lit.)

solubility

benzene: slightly soluble(lit.), pyridine: slightly soluble(lit.)

density

2.8 g/mL at 25 °C (lit.)

Quality Level

100

相关类别

Application

  • Anion exchange dynamics in the capture of perchlorate by a cationic Ag-based MOF：研究银基金属有机骨架捕获高氯酸盐的阴离子交换动力学和结构转换(Colinas et al., 2017)。

pictograms

Flame over circleCorrosion
GHS03,GHS05

signalword

Danger

hcodes

H272,H314

Hazard Classifications

Ox. Sol. 2 - Skin Corr. 1B

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ7143
MKCW2275
MKCV6734
MKCT6666
MKCS7083

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C Rentel et al.
Analytical chemistry, 70(20), 4394-4400 (1998-10-31)
In LC/MS, nonpolar substances in the majority of cases cannot be ionized by standard electrospray ionization (ESI) because they obviously lack a site for protonation or deprotonation. The ionization of carotenoids and tocopherols can be greatly enhanced by the addition
E Petráková et al.
Carbohydrate research, 233, 101-112 (1992-09-02)
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
Masafumi Harada et al.
Journal of colloid and interface science, 339(2), 373-381 (2009-09-08)
Metal particles of silver (Ag) were synthesized by the photoreduction of silver perchlorate (AgClO(4)) in water-in-ionic liquid (ILs) microemulsions consisting of Tween 20, water and ionic liquids. The ILs were tetrafluoroborate anions associated with the cations 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF(4)]) and
Ken Sakai et al.
Acta crystallographica. Section B, Structural science, 60(Pt 3), 255-262 (2004-05-19)
The third crystal structure containing the hydroxo-bridged cis-diammineplatinum(II) dimer has been determined for a perchlorate salt of the complex, [Pt(2)(NH(3))(4)(micro-OH)(2)](ClO(4))(2). However, the dinuclear cations in the nitrate and the carbonate salts, [Pt(2)(NH(3))(4)(micro-OH)(2)](NO(3))(2) [Faggiani, Lippert, Lock & Rosenberg (1977). J. Am.
Glycosylation via Cp2ZrCl2/AgClO4-mediated activation of anomeric sulfoxides.
P Wipf et al.
The Journal of organic chemistry, 66(23), 7910-7914 (2001-11-10)
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