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Merck
CN

675644

三氧化铬(VI)

99.99% trace metals basis

别名:

铬酸酐

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经验公式(希尔记法):
CrO3
化学文摘社编号:
分子量:
99.99
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
215-607-8
MDL number:
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InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N

SMILES string

O=[Cr](=O)=O

assay

99.99% trace metals basis

form

powder or flakes

reaction suitability

reagent type: oxidant

mp

196 °C (dec.) (lit.)

application(s)

battery manufacturing

Quality Level

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General description

氧化铬(VI) (CrO3)是六价铬,主要用作氧化剂。它可以氧化芳环中的C-H键,从烷基苯形成苯甲酸。可通过将浓硫酸加入重铬酸钾来制备。

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 1B - Ox. Sol. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Respiratory system

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chromium Oxidations in Organic Chemistry (2011)
Sara L Holland et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(6), 1764-1767 (2010-07-20)
Toxicity of the environmental carcinogen chromate is known to involve sulfur starvation and also error-prone mRNA translation. Here we reconcile those facts using the yeast model. We demonstrate that: (i) cysteine and methionine starvation mimic Cr-induced translation errors, (ii) genetic
Evidence for the protective effect of ascorbic acid (vitamin C) in treatment with gamma-rays and chromium (VI) oxide (CrO3) in somatic cells of Drosophila.
O Olvera et al.
Mutation research, 346(1), 19-21 (1995-01-01)
Kyung-Hwa Son et al.
Journal of toxicology and environmental health. Part A, 67(13), 1027-1049 (2004-06-19)
CrO3 is cytotoxic for human epithelial 293 kidney cells over a narrow concentration range of approximately 2-8 microM (D50 approximately 3.0 microM); significantly greater toxicity is observed in clonogenic assays (D50 approximately 0.1-1.0 microM). Survival of a small fraction of
Sethsiri S Samaratunga et al.
Environmental science and pollution research international, 15(1), 27-30 (2008-03-01)
Chromium enters into the aquatic environment as a result of effluent discharge from steel works, electroplating, leather tanning industries and chemical industries. As the Cr(VI) is very harmful to living organisms, it should be quickly removed from the environment when

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