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关于此项目
经验公式(希尔记法):
C32H22O2
化学文摘社编号:
分子量:
438.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
assay
97%
optical activity
[α]20/D -314°, c = 1 in chloroform
mp
199-203 °C
functional group
phenyl
SMILES string
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI key
NDTDVKKGYBULHF-UHFFFAOYSA-N
Application
(S)-VANOL 是一种拱形联芳基配体,可用于合成配位配合物,例如(dppe)Pt(S-VANOL)[dppe =双(二苯基膦基)乙烷]和(S,S-chiraphos)Pt (S-VANOL)[Chiraphos=2,3-双(二苯基膦基)丁烷]。
VANOL 已被证明是催化不对称 Diels-Alder、亚胺羟醛和叠氮化反应的出色配体。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
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相关内容
The research areas of interest to the Wulff group include enantioselective catalysis, mechanisms of asymmetric catalysis, macromolecular chemistry, Fischer carbene complexes in organic synthesis and the total synthesis of natural products.
Synthesis and characterization of chiral diphosphine platinum (II) VANOL and VAPOL complexes.
Becker JJ, et al.
Organometallics, 22(16), 3245-3249 (2003)
Bao. J. et al.
Journal of the American Chemical Society, 118, 3392-3392 (1996)
Su Yu et al.
Organic letters, 7(3), 367-369 (2005-01-28)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 676098-250MG | 04061832624426 |

