678732
三氯化硼
1.0 M in toluene
别名:
Boron chloride, Trichloroborane
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关于此项目
经验公式（希尔记法）:
BCl3
化学文摘社编号:
分子量:
117.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
Concentration:
1.0 M in toluene
Quality Level
concentration
1.0 M in toluene
density
0.909 g/mL at 25 °C
SMILES string
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
General description
Boron trichloride (BCl3) is a boron halide typically used as a reagent in organic synthesis for the cleavage of C-O bonds in ethers.
Application
Boron trichloride (BCl3) can be used as a reactant in the preperation of borazine-linked polymer [BLP-10(Cl)] by thermal decomposition with benzidine for gas storage and purification.
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signalword
Danger
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-2.0 °F
flash_point_c
-18.9 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Highly selective CO 2/CH 4 gas uptake by a halogen-decorated borazine-linked polymer
Reich TE, et al.
Journal of Materials Chemistry, 22(27), 13524-13528 (2012)
Conversion of aromatic aldehydes to gem-dichlorides using boron trichloride. A new highly efficient method for preparing dichloroarylmethanes.
Kabalka G W and Wu Z
Tetrahedron Letters, 41(5), 579-581 (2000)
George W Kabalka et al.
The Journal of organic chemistry, 73(7), 2668-2673 (2008-03-06)
A boron trihalide mediated alkyne-aldehyde coupling reaction leading to stereodefined 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes is described. The study led to the discovery of a direct substitution of hydroxyl groups by stereodefined alkenyl moieties using alkenylboron dihalides. During the investigation, it was also discovered
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 678732-800ML | 04061838128805 |
| 678732-100ML | 04061832748627 |