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Merck
CN

679259

Sigma-Aldrich

硅酸甲酯

deposition grade, ≥98%, ≥99.9% trace metals basis

别名:

四甲氧基硅烷

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关于此项目

线性分子式:
Si(OCH3)4
化学文摘社编号:
分子量:
152.22
Beilstein:
1699658
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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等级

deposition grade

蒸汽密度

5.25 (vs air)

蒸汽压

13 hPa ( 20 °C)

方案

≥98%
≥99.9% trace metals basis

表单

liquid

折射率

n20/D 1.368 (lit.)

沸点

121-122 °C (lit.)

mp

−4 °C (lit.)

密度

1.023 g/mL at 25 °C (lit.)

SMILES字符串

CO[Si](OC)(OC)OC

InChI

1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3

InChI key

LFQCEHFDDXELDD-UHFFFAOYSA-N

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应用

用于掺铬硅酸盐的溶胶-凝胶合成以及六方介孔氧化硅层的形成。

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

78.8 °F - closed cup

闪点(°C)

26 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

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Zian Lin et al.
Chemical communications (Cambridge, England), 47(34), 9675-9677 (2011-07-30)
An inorganic-organic hybrid affinity monolithic column was synthesized by a novel "one-pot" approach. The resulting hybrid affinity monoliths have potential applications in specific recognition and enrichment of glycoproteins.
Akhilesh Rai et al.
Langmuir : the ACS journal of surfaces and colloids, 26(6), 4152-4159 (2009-12-17)
We report an elegant and simple method to fabricate uniform silica films with controlled thickness, roughness, and hydrophilicity using nanogram quantities of silicatein, a protein involved in silica synthesis in sponges. The formation of uniform silica films was achieved by
Microemulsion-mediated self-assembly and silicification of mesostructured ferritin nanocrystals.
Elizabeth M Lambert et al.
Angewandte Chemie (International ed. in English), 49(24), 4100-4103 (2010-04-29)
Yonghao Xiu et al.
Journal of colloid and interface science, 326(2), 465-470 (2008-07-29)
A method for the preparation of inorganic superhydrophobic silica coatings using sol-gel processing with tetramethoxysilane and isobutyltrimethoxysilane as precursors is described. Incorporation of isobutyltrimethoxysilane into silica layers resulted in the existence of hydrophobic isobutyl surface groups, thereby generating surface hydrophobicity.
Yun Tian et al.
Electrophoresis, 29(4), 960-970 (2008-01-24)
A novel calix[4] open-chain crown ether (p-tert-butylcalix[4]arene-1,3-bis(allyloxyethy) ether)-modified, organic-inorganic hybrid silica-based monolithic column possessing vinyl ligands for CEC is described. The monolithic silica matrix containing a vinyl functionality was synthesized by in situ cocondensation of tetramethoxysilane (TMOS) and vinyltrimethoxysilane (VTMS)

商品

From Form to Function: Molding Porous Materials in Three Dimensions by Colloidal Crystal Templating

Deposition Grade Silanes, fully characterized by chemical analysis and nuclear magnetic resonance (NMR) with greater than 98% purity, for Sol-Gel Processes.

涉及到反应性有机硅化学的研究已聚焦于纯硅和杂合材料的生产、氢化硅烷化、开环和原子转移聚合,以及具有受控立体化学的聚合和缩合反应。

Reactive silicone chemistry: Focus on pure silicon production, polymerizations, and controlled stereochemistry reactions.

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