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关于此项目
经验公式(希尔记法):
C56H41O4PSi2
化学文摘社编号:
分子量:
865.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
assay
96%
form
solid
optical activity
[α]22/D +210°, c = 1 in chloroform
mp
188-193 °C
functional group
phosphate
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI
1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key
BDQOCXQVIFQJRK-UHFFFAOYSA-N
Application
(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:
- In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
- In the exo-selective cyclization of mupirocin methyl ester.
- In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
商品
TRIP and TiPSY Chiral Phosphoric Acid Catalysts
TRIP和TiPSY手性磷酸催化剂
Experimental and Computational Studies on Regiodivergent Chiral Phosphoric Acid Catalyzed Cycloisomerization of Mupirocin Methyl Ester
Wang S, et al.
Chemistry?A European Journal , 26(8), 4583-4591 (2020)
Parallel Kinetic Resolution of Unsymmetrical Acyclic Aliphatic syn-1, 3-Diols
Yang H and Zheng W
Organic Letters, 21(13), 5197-5200 (2019)
Diastereo-and Enantioselective Construction of Biologically Important Chiral 1, 3-Dioxolochroman Frameworks via Catalytic Asymmetric [4+ 2] Cycloaddition
Tu M, et al.
The Journal of Organic Chemistry, 85(8), 5403-5415 (2020)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 680184-100MG | 04061833549865 |
