680850
双(4-氯苄基)偶氮二甲酸酯
97%
别名:
DCAD, 偶氮二甲酸二(对氯苄基)酯
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关于此项目
经验公式（希尔记法）:
C16H12Cl2N2O4
化学文摘社编号:
分子量:
367.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
97%
Form:
solid
Quality Segment
assay
97%
form
solid
mp
108-112 °C
functional group
azo, chloro
SMILES string
O=C(/N=N\C(OCC1=CC=C(Cl)C=C1)=O)OCC2=CC=C(Cl)C=C2
InChI
1S/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2/b20-19-
InChI key
UIFGGABIJBWRMG-VXPUYCOJSA-N
General description
Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.
Application
双(4-氯苄基)偶氮二甲酸酯 (DCAD) 是 DEAD 和 DIAD 的新型稳定固体替代物，可用于多种 Mitsunobu 偶联反应，生成易于分离并且可回收利用的副产物肼。
Reactant for preparation of:
- Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters
- Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium
- DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions
