680990
1,1′-双[(2R,5R)-2,5-二乙基膦烷基]二茂铁
别名:
R,R-Et-Ferrocelane™
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关于此项目
经验公式（希尔记法）:
C26H40FeP2
化学文摘社编号:
分子量:
470.39
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Segment
optical activity
[α]20/D +380°, c = 1 in chloroform
mp
85-91 °C
functional group
phosphine
SMILES string
C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4
InChI
1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1
InChI key
CPUKIDAUDCWIRT-QULUYMGFSA-N
Application
1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:
- As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
- As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.
Legal Information
与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable