681539
(S)-(–)-3-3′-双(3,5-双(三氟甲基)苯基)-1,1′-二-2-萘酚
95%
别名:
(1S)-3,3′-双[3,5-双(三氟甲基)苯基]1,1′-联萘-2,2′-二醇
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选择尺寸
关于此项目
经验公式（希尔记法）:
C36H18F12O2
化学文摘社编号:
分子量:
710.51
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C36H18F12O2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29(31(27)49)30-26-8-4-2-6-18(26)14-28(32(30)50)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49-50H
SMILES string
Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)-c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6cc(cc(c6)C(F)(F)F)C(F)(F)F
InChI key
PGXMYJSTCAQJBY-UHFFFAOYSA-N
assay
95%
form
(Powder or Crystals or Solid or Chunks)
optical activity
[α]22/D -56°, c = 1 in chloroform
mp
215-219 °C
functional group
fluoro
Quality Level
Application
(S)-(-)-3-3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol reacts with tin(IV) chloride to form a Sn(IV) aryloxide Lewis acid, which can catalyze asymmetric Diels-Alder reactions.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Design of chiral tin (IV) aryloxide as a mild Lewis acid catalyst for enantioselective Diels-Alder reaction.
Kano T, et al.
Tetrahedron Letters, 47(6), 873-875 (2006)
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