686441
氯二羰基(1,2,3,4,5-五苯基环戊二烯基)钌(II)
别名:
二羰基氯[(1,2,3,4,5,-η)-1,2,3,4,5-五苯基环-2,4-戊二烯-1-基)]钌
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关于此项目
经验公式（希尔记法）:
C37H25ClO2Ru
化学文摘社编号:
分子量:
638.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
form
solid
reaction suitability
core: ruthenium, reagent type: catalyst
mp
152-167 °C
SMILES string
Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
InChI
1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
InChI key
NGSBLRJKXUHTOC-UHFFFAOYSA-M
Application
用于以下反应的反应物：
用以下催化剂：
- 环戊二烯基钌二羰基催化剂的合成
- 配体交换
- 具有配位C:C键的环戊二烯基钌烷氧羰基配合物的形成
用以下催化剂：
- （S）-仲醇的选择性动态动力学拆分
- 新烟碱类农药衍生物的立体选择性合成
- 3,5-二取代哌啶的发散不对称合成
Legal Information
Kanata Chemical Technologies, Inc. 产品
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Belén Martín-Matute et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(23), 6053-6061 (2006-06-27)
Highly efficient synthesis of enantiopure diacetates of 2,4-pentanediol and 2,5-hexanediol starting from commercially available mixtures of the diols (dl/meso approximately 1:1) has been realized by combining a fast ruthenium-catalyzed epimerization with an enzymatic transesterification. The in situ coupling of these
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 686441-1G | 04061832759494 |
| 686441-250MG | 04061833550397 |