688886
乙酰乙酸甲酯
Arxada quality, ≥99% (GC)
别名:
3-丁酮酸甲酯, 乙酰醋酸甲酯
质量水平
方案
≥99% (GC)
表单
liquid
自燃温度
536 °F
质量
Arxada quality
制造商/商品名称
Arxada AG
杂质
≤0.10% acid (as acetic acid)
≤0.10% water
颜色
APHA: ≤20
折射率
n20/D 1.419 (lit.)
沸点
169-170 °C/70 mmHg (lit.)
mp
−80 °C (lit.)
密度
1.076 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)CC(C)=O
InChI
1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3
InChI key
WRQNANDWMGAFTP-UHFFFAOYSA-N
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警示用语：
Danger
危险声明
危险分类
Eye Dam. 1
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Karl Sörelius et al.
Circulation, 130(24), 2136-2142 (2014-11-08)
Mycotic aortic aneurysm (MAA) is a rare and life-threatening disease. The aim of this European multicenter collaboration was to study the durability of endovascular aortic repair (EVAR) of MAA, by assessing late infection-related complications and long-term survival. All EVAR treated
Marianne Ernst et al.
Applied microbiology and biotechnology, 66(6), 629-634 (2004-11-19)
A whole-cell biotransformation system for the reduction of prochiral carbonyl compounds, such as methyl acetoacetate, to chiral hydroxy acid derivatives [methyl (R)-3-hydroxy butanoate] was developed in Escherichia coli by construction of a recombinant oxidation/reduction cycle. Alcohol dehydrogenase from Lactobacillus brevis
S Aramaki et al.
Journal of inherited metabolic disease, 14(1), 63-74 (1991-01-01)
The concentrations of 2-methylacetoacetate, 2-methyl-3-hydroxybutyrate and tiglylglycine were determined by gas chromatography-mass spectrometry in urine collected before and for 8 h after loading with 100 mg of isoleucine per kg of body weight. The sum of 2-methylacetoacetate and 2-butanone, a
B H Robinson et al.
The Journal of pediatrics, 95(2), 228-233 (1979-08-01)
A female child presented at one year of age with a febrile illness and loose stools, then developed severe ketoacidosis with vomiting; an apparent salicylate level of 11 mg/dl was measured. A sibling had died in similar circumstances nine years
Solvej Siedler et al.
Applied microbiology and biotechnology, 93(4), 1459-1467 (2011-10-18)
Optimization of yields and productivities in reductive whole-cell biotransformations is an important issue for the industrial application of such processes. In a recent study with Escherichia coli, we analyzed the reduction of the prochiral β-ketoester methyl acetoacetate by an R-specific
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