689017
N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺
≥98.5% (T)
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关于此项目
经验公式（希尔记法）:
C6H11F3N2O2S
化学文摘社编号:
分子量:
232.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
≥98.5% (T)
Form:
powder
产品名称
N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺, ≥98.5% (T)
InChI
1S/C6H11F3N2O2S/c7-6(8,9)14(12,13)11-4-5-2-1-3-10-5/h5,10-11H,1-4H2/t5-/m0/s1
SMILES string
FC(F)(F)S(=O)(=O)NC[C@@H]1CCCN1
InChI key
RIWFUAUXWIEOTK-YFKPBYRVSA-N
assay
≥98.5% (T)
form
powder
optical activity
[α]/D +13±1°, c = 1 in methanol
optical purity
ee: ≥98.5%
functional group
amine
fluoro
Quality Level
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Liansuo Zu et al.
Organic letters, 10(6), 1211-1214 (2008-02-15)
Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the organocatalyst is that it can be recovered from the reaction mixtures by
Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.
Wei Wang et al.
Angewandte Chemie (International ed. in English), 44(9), 1369-1371 (2005-01-25)
Liansuo Zu et al.
Organic letters, 8(14), 3077-3079 (2006-06-30)
[reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ketones and aldehydes with nitroolefins in water. The organocatalyst is conveniently recovered from the reaction mixtures
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