68916
(R)-(-)-S-甲基-S-苯亚磺酰亚胺
≥99.0% (GC)
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关于此项目
经验公式（希尔记法）:
C7H9NOS
化学文摘社编号:
分子量:
155.22
UNSPSC Code:
12352002
PubChem Substance ID:
MDL number:
assay
≥99.0% (GC)
form
solid
optical activity
[α]/D −28.5±3, c = 1 in acetonitrile
SMILES string
C[S@@](=N)(=O)c1ccccc1
InChI
1S/C7H9NOS/c1-10(8,9)7-5-3-2-4-6-7/h2-6,8H,1H3/t10-/m1/s1
InChI key
YFYIDTVGWCYSEO-SNVBAGLBSA-N
Other Notes
新型 C1-对称单砜亚胺配体，可用于对映选择性杂 Diels-Alder 反应：喹啉类 C1-对称砜亚胺反应可生成光学纯度高达 96% 的环加合物
Carsten Bolm et al.
Chemical communications (Cambridge, England), (22), 2826-2827 (2003-12-04)
Quinoline-based C1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee.