689386
甲醛二丁基缩醛
puriss., ≥97.0% (GC)
别名:
Butylal, Dibutoxymethane
等级
puriss.
质量水平
方案
≥97.0% (GC)
表单
liquid
杂质
≤0.25% water
折射率
n20/D 1.406
密度
0.835 g/mL at 20 °C
官能团
ether
SMILES字符串
CCCCOCOCCCC
InChI
1S/C9H20O2/c1-3-5-7-10-9-11-8-6-4-2/h3-9H2,1-2H3
InChI key
QLCJOAMJPCOIDI-UHFFFAOYSA-N
一般描述
Formaldehyde dibutyl acetal is an acetal used in the manufacture of synthetic resins, antiseptics, deodorants, and fungicides. It is also used as a fuel additive to increase the octane number of gasoline or the n-cetane number of diesel fuels and reduce smoke and particulate emissions.
应用
Formaldehyde dibutyl acetal is a halogen-free and less toxic solvent that can be used to solubilize commercial low-density polyethylene (LDPE) samples to analyze molecular weight distribution using gel permeation chromatography (GPC). It can also be used as a reactant to prepare butoxymethyltriphenylphosphonium iodide, which is used for carbon homologation and also as a useful key intermediate in organic synthesis.
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
143.6 °F - closed cup
闪点(°C)
62 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Facile synthesis of α-alkoxymethyltriphenylphosphonium iodides: new application of PPh 3/I 2
Gondal HY, et al.
Chemistry Central Journal, 12(1), 1-10 (2018)
Selected physicochemical properties of dibutoxymethane
P-T Marcela and Szafranski AM
Journal of Chemical and Engineering Data, 45(6), 988-990 (2000)
Characterization of low-density polyethylene in dibutoxymethane by high-temperature gel permeation chromatography with triple detection
Boborodea A, et al.
Chromatographia, 79(15), 971-976 (2016)
Vieille-Petit, L.; et al.
Chemical Communications (Cambridge, England), 3783-3783 (2009)
Michele Gatti et al.
Journal of the American Chemical Society, 131(27), 9498-9499 (2009-06-19)
Two saturated N-heterocyclic carbene ligands with substituted naphthyl side chains were used for the preparation of Blechert-type ruthenium metathesis precatalysts. The resulting conformers of the complexes were separated and unambiguously assigned by X-ray diffraction studies. All new complexes were compared
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