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Merck
CN

689483

1-乙基-3-甲基咪唑乙酸酯

97%

别名:

EMIM Ac

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关于此项目

经验公式(希尔记法):
C8H14N2O2
化学文摘社编号:
分子量:
170.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

1-乙基-3-甲基咪唑乙酸酯, 97%

InChI

1S/C6H11N2.C2H4O2/c1-3-8-5-4-7(2)6-8;1-2(3)4/h4-6H,3H2,1-2H3;1H3,(H,3,4)/q+1;/p-1

SMILES string

CC([O-])=O.CCn1cc[n+](C)c1

InChI key

XIYUIMLQTKODPS-UHFFFAOYSA-M

assay

≥96.5% (HPLC)
97%

form

liquid

impurities

≤5.0% water

refractive index

n20/D 1.501

mp

>30 °C (product can occur as an undercooled melt)

density

1.101 g/cm3 at 20 °C

Quality Level

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Application

1-乙基-3-甲基咪唑鎓乙酸盐用于制备离子液体铁磁流体(ILF)。

General description

1-乙基-3-甲基咪唑鎓乙酸盐是一种非质子咪唑鎓室温离子液体,是纤维素溶剂。用1-乙基-3-甲基咪唑乙酸盐预处理蔗渣可通过酶促糖化反应生成葡萄糖。

1-乙基-3-甲基咪唑乙酸盐可作为催化剂在无酸条件下催化纤维素乙酰化反应。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2 - Skin Sens. 1B

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

327.2 °F - closed cup

flash_point_c

164 °C - closed cup

ppe

Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Stable and water-tolerant ionic liquid ferrofluids.
Jain N, et al.
ACS Applied Materials & Interfaces, 3(3), 662-667 (2011)
Proton transfer and polarity changes in ionic liquid?water mixtures: a perspective on hydrogen bonds from ab initio molecular dynamics at the example of 1-ethyl-3-methylimidazolium acetate?water mixtures?Part 1
Brehm, Martin, et al.
Physical Chemistry Chemical Physics, 14.15, 5030-5044 (2012)
Interactions of Ionic Liquids with Polysaccharides 1. Unexpected Acetylation of Cellulose with 1?Ethyl?3?methylimidazolium Acetate
Kohler, Sarah, et al.
Macromolecular Rapid Communications, 28.24, 2311-2317 (2007)
Tobiasz Gabryś et al.
Carbohydrate polymers, 254, 117436-117436 (2020-12-29)
The paper presents the results of a study on the preparation of cellulose-based composite fibres (CEL) with graphene oxide addition (GO). Composite fibres (GO/CEL) were prepared via the wet spinning method from CEL solutions in 1-ethyl-3-methylimidazolium acetate (EMIMAc) that contained
Neutron diffraction, NMR and molecular dynamics study of glucose dissolved in the ionic liquid 1-ethyl-3-methylimidazolium acetate
Youngs, Tristan GA, et al.
Chemical Science, 2.8, 1594-0605 (2011)

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