690945
N,N-二乙基乙酰乙酰胺
Arxada quality, 98.0-100.3 % (w/w) (T)
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线性分子式:
CH3COCH2CON(C2H5)2
化学文摘社编号:
分子量:
157.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-792-3
Beilstein/REAXYS Number:
636486
MDL number:
产品名称
N,N-二乙基乙酰乙酰胺, Arxada quality, 98.0-100.3 % (w/w) (T)
InChI key
NTMXFHGYWJIAAE-UHFFFAOYSA-N
InChI
1S/C8H15NO2/c1-4-9(5-2)8(11)6-7(3)10/h4-6H2,1-3H3
SMILES string
CCN(CC)C(=O)CC(C)=O
form
liquid
quality
Arxada quality
manufacturer/tradename
Arxada AG
concentration
98.0-100.3 % (w/w) (T)
impurities
≤0.30% water
≤4.00 g/L free amine
density
0.994 g/mL at 20 °C (lit.)
Quality Level
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Application
N,N-Diethylacetoacetamide is a β-dicarbonyl compound that can be used to synthesize potent calcium channel blockers such as 2,6,6-trimethyl-3-diethylaminocarbonyl-4-aryl-5-oxo-1,4,5,6,7,8-hexahydroquinoline derivatives and N,N-diethyl-2,6,6-trimethyl-4-(3-nitrophenyl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxamide. It can also undergo Michael addition in the presence of bis(2,4-pentanedionato)nickel(II) catalyst.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
201.2 °F - closed cup
flash_point_c
94 °C - closed cup
ppe
Eyeshields, Gloves
N, N-Diethyl-2, 6, 6-trimethyl-4-(3-nitrophenyl)-5-oxo-1, 4, 5, 6, 7, 8-hexahydroquinoline-3-carboxamide.
Linden A
Acta Crystallographica Section C, Crystal Structure Communications, 58(7), 436-438 (2002)
Studies on 3-Diethyl-aminocarbonyl-1, 4; 5, 6, 7, 8-hexahydroquinoline Derivatives and their Calcium Channel Antagonistic Activities in vitro.
K?smetli E
Arzneimittelforschung, 54(07), 371-375 (2004)
Nickel-catalyzed Michael additions of. beta.-dicarbonyls.
Nelson JH
The Journal of Organic Chemistry, 45(7), 1246-1249 (1980)
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