692336
RuCl2[(R)-(DM-SEGPHOS®)][(R,(R))-(DPEN)]
别名:
二氯[(R)-5,5′-双[二(3,5-二甲苯基)膦]-4,4′-二-1,3-苯并二噁茂][(1R,2R)-1,2-二苯基乙二胺]钌(II)
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关于此项目
经验公式（希尔记法）:
C60H60Cl2N2O4P2Ru
化学文摘社编号:
分子量:
1107.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
form
powder
reaction suitability
reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation
storage temp.
2-8°C
SMILES string
Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
InChI
1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
InChI key
FOEKPXQPRAIJRW-ODQAEMFESA-L
Application
RuCl2[(R)-(DM-SEGPHOS®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.
Legal Information
与 Takasago 合作销售，仅用于研究目的。日本注册号 3148136，日本申请号 19970359654
SEGPHOS is a registered trademark of Takasago Intl. Corp.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable