692352
双(六甲基二硅叠氮)镁
97%
别名:
Mg(HMDS)2, 双(六甲基二硅杂叠氮基)镁
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关于此项目
经验公式（希尔记法）:
C12H36MgN2Si4
化学文摘社编号:
分子量:
345.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
97%
Form:
solid
产品名称
双(六甲基二硅叠氮)镁, 97%
InChI
1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2
SMILES string
C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI key
WYPTZCBYSQFOQS-UHFFFAOYSA-N
assay
97%
form
solid
mp
121-124 °C
Quality Level
Application
双（六甲基二硅氮化物）镁是合成 rac -丙交酯大范围配基配合物的重要前体。 也可用于合成 ItBu:Mg[N(SiMe3)2]2，其中 I t Bu =（1,3-二- 叔 -丁基咪唑-2-亚基），该催化剂用于碳化二亚胺加胺的鸟苷酸化反应。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Highly active magnesium initiators for ring-opening polymerization of rac-lactide.
Wang L and Ma H
Macromolecules, 43(16), 6535-6537 (2010)
Stereoselectivity switch between zinc and magnesium initiators in the polymerization of rac-lactide: different coordination chemistry, different stereocontrol mechanisms.
Wang H, et al.
Macromolecules, 47(22), 7750-7764 (2014)
Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks.
Whitehorne T J, et al.
Dalton Transactions, 43(17), 6339-6352 (2014)
Dong Chen et al.
Nanoscale, 11(48), 23173-23181 (2019-11-30)
CoSe2 materials with different nanostructures are used as pseudocapacitive Mg-storage cathodes, which exhibit fast solid-state Mg2+ ions diffusion kinetics. In this work, CoSe2 with different nanostructures including hollow microspheres (H-CoSe2), nano-polyhedra (P-CoSe2) and nanorods (R-CoSe2) are fabricated by using facile
Catalytic C?N bond formation in guanylation reaction by N-heterocyclic carbene supported magnesium (II) and zinc (II) amide complexes.
Baishya A, et al.
Journal of Organometallic Chemistry, 769, 112-118 (2014)
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